Predict the major most products of the following reactions or reaction sequences. Mechanisms are not required for your answers to these questions. In sequences, partial credit can be earned by correctly identifying products of each step in the sequence. 1) NaH, THF H-= 2) 3) H₂0Ⓒ 0-H- 1) PhMgBr, ether 2) H₂O Ⓒ b) d) HO OTS OH [(Pr)₂CuCN]Li₂, THF CHO OH OH MeOH H₂0 cat. A) O3. CH₂Cl₂, -78°C B) (CH3)2S

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter22: Carbonyl Alpha-substitution Reactions
Section22.SE: Something Extra
Problem 26MP: Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium...
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Predict the major most products of the following reactions or reaction sequences. Mechanisms are
not required for your answers to these questions. In sequences, partial credit can be earned by correctly
identifying products of each step in the sequence.
1) NaH, THF
H-=
2)
3) H₂0Ⓒ
0-H-
1) PhMgBr, ether
2) H₂O Ⓒ
b)
d)
HO
OH
OTS
[(Pr)₂CuCN)Li₂, THF
CHO
OH OH
MeOH
H₂0
cat.
A) O3. CH₂Cl₂, -78°C
B) (CH3)2S
Transcribed Image Text:Predict the major most products of the following reactions or reaction sequences. Mechanisms are not required for your answers to these questions. In sequences, partial credit can be earned by correctly identifying products of each step in the sequence. 1) NaH, THF H-= 2) 3) H₂0Ⓒ 0-H- 1) PhMgBr, ether 2) H₂O Ⓒ b) d) HO OH OTS [(Pr)₂CuCN)Li₂, THF CHO OH OH MeOH H₂0 cat. A) O3. CH₂Cl₂, -78°C B) (CH3)2S
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