PART B: Using electron pushing arrows give the mechanism for the reaction below. Clearly indicate ALL Intermediates and Products. Assume SN1 pathway. The following is a reaction in the biosynthesis of morphine in opium poppies. H3CO. H3CO HO CH3 -CH3 CH3 H3CO H₂CO CH3

PART B: Using electron pushing arrows give the mechanism for the reaction below. Clearly indicate ALL Intermediates and Products. Assume SN1 pathway. The following is a reaction in the biosynthesis of morphine in opium poppies. H3CO. H3CO HO CH3 -CH3 CH3 H3CO H₂CO CH3

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter10: Organohalides

Section10.SE: Something Extra

Problem 19MP: The formation of Br2 from NBS first involves the reaction of NBS with HBr to form an iminol...

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Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

PART B:
Using electron pushing arrows give the mechanism for the reaction below.
Clearly indicate ALL Intermediates and Products. Assume SN1 pathway.
The following is a reaction in the biosynthesis of morphine in opium poppies.
H3CO
H₂CO
HO
CH3
S
-CH3
CH3
H₂CO
CH3
H₂CO

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