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- Which one of the following is NOT a possible completion of the following reaction? CH,OH но но 1. NABH, 2. acidic workup но H- OH ČH,OH A. D-talose B. D-tagatose C. the C-3 epimer of D-gulose D. the C-5 epimer of L-psicose E. the C-5 epimer of L-allose F. the C-3 epimer of D-idose G. g. the C-3 epimer of L-glucose A В E F O GCircle the reducing sugars. OH но но OH HO но но но но HO но OH OH но HO OH OH ноcomplete the reaction 68
- Identify the products obtained by the hydrolysis of the given compound. оо | | -COC- Select one: O a. one molecule of dibenzoic acid and one molecule of benzene O b. one molecule of benzene and one molecule of a carboxylic acid O c. two molecules of phenol O d. two molecules of benzoic acid4. Which choice shows the correct products of the following hydrolysis reaction? HCI se HOLLO ? H₂O twite i NH₂ don OH (a) (d) locios en Hol tone NH3 HO NH₂ (b) COD love e NH3 H₂N oi (e) le can be labeled as (c) Add to a withleft 4. Consider the following equilibrium: 29925610 + Aga weak and Sung base Bast CORS + 1ght base: Strong ad d AddOH ress stable OH Is the carboxylate anion (CH3CH₂COO) an appropriate base to deprotonate the alcohol? A) yes, because the equilibrium favors the left side B) yes, because the equilibrium favors the right side C) no, because the equilibrium favors the left side D) no, because the equilibrium favors the right side OH COO bas
- What type(s) of catalysis is/are present in the enzymatic reaction below? SCOA H-His CH SCOA Asp CH COASH CH: CO HO-C-COO" HO-C-COO H-CH, acetyl-CeA SCOA CH, CH; CH COO COO COO oxaloacetate an intermediate citrate Select one or more: a. general acid b. general base C. metal ion d. specific base e. nucleophilic f. specific acidComplete both reactions please! Draw Product CN NH acid catalyst 1. CH₂MgBr/THF 2. H30*ol de C 3. Caffeine is an alkaloid, meaning alkali- or base-like. Circle functional groups in the molecule which would make react as a base. CH3 CH3 a. O b. O 4. Write the equations that account for what happens in the hydrolysis of acetamide O || (CH₂C-NH₂) in (a) acid and in (b) base. woled mode) N I T CH3 H Caffeine custom page 114
- ONANO (a) Circle the two compounds that are not carboxylic acid derivatives. Circle only two. CONHCH3 CN =NOH NH COCI (b) Circle the two compounds that can be hydrolyzed to a ketone in aqueous acid. Circle only two. N-PH (c) Circle the two compounds that can be converted to an aldehyde by reduction using DIBAL (also known as DIBAL-H). Circle only two. .CHO он CN (d) Circle the two most reactive compounds with water. Circle only two DEt OMe NH2 CH;CH,CN (e) Circle the strongest acid. [2 marks] CO.Et CO-H NO2 CHO (1) Circle ethyl benzoate and maleic anhydride. COCH,CH, .Co.CH,CH3 (g) Circle the two compounds that can be reduced to an amine using NaBH4. Circle only two. 'NH2 CN NH14. Complete the following synthesis. HCI, H₂O10:54 ← Question 21 of 32 Draw the major product of this reaction. Ignore inorganic byproducts. Submit Assume that the water side product is continuously removed to drive the reaction toward products. (CH3)2NH, TSOH Select to Draw | I I