Para-substituted product was produced when phenol reacts with cyclohexanecarbonyl bromide in the presence of AIB13. -Br Cyclohexanecarbonyl bromide (i) Outline the mechanism for this reaction. (ii) Draw the alternative substituted product formed.

Para-substituted product was produced when phenol reacts with cyclohexanecarbonyl bromide in the presence of AIB13. -Br Cyclohexanecarbonyl bromide (i) Outline the mechanism for this reaction. (ii) Draw the alternative substituted product formed.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions

Section19.SE: Something Extra

Problem 28VC

See similar textbooks

Related questions

Q: Consider the following reaction: PCI5(g) PCI3(g) + Cl2(g) If 2.82x10 2 moles of PCI5(g), 0.301 moles...

A: Given Moles at equilibrium PCl5 = 2.82 * 10-2 moles PCl3 = 0.301moles Cl2 = 0.407 moles Volume = 18...

Q: Identify the suitable reagents for the following: 1) Вн, THF 2)H,O2, NaOH

Q: In the esterification of isoamyl acetate using isoamyl alcohol and acetic acid, a small volume of mi...

A: The esterification is a process in which an alcohol combines with acetic acid to form ester in an ac...

Q: Encircle and identify the region in the molecular structure that pertains to a specific functional g...

Q: H d a H3C- e EN H

Q: The rate of any chemical reaction can be determined by observing the amount of product formed in a...

A: Rate of reaction is defined as change of concentrations with respect to time .

Q: Chemistry Question

Q: Name a chemical test to differentiate 3-methylpentan-3-ol from 2-methylpentan-3-ol. Provide a chemic...

A: To differentiate between the 3-methylpentan-3-ol from 2-methylpentan-3-ol we use a test named as Luc...

Q: hydrocarbons

Q: A given 50.0 ml animal urine sample was analyzed for its ammonium content. If after analysis it was ...

Q: Why do scientists study and synthesize new transuranium elements in the laboratory? What are the use...

Q: Active Site 2 3 HN- NH2 2-OPO 4 Но Но- HO OHa 1

A: In the given question, the active side contains many functional moieties.

Q: • If there is reaction, write a complete chemical equation (reactants products) (Don't forget to inc...

Q: 1. Why is the calibration curve prepared using a higher concentration of Fe"? - n hot all of the SCN...

A: Since you have asked multiple questions we will answer the first one for you. To get the remaining q...

Q: Prelaboratory Assignment: Qualitative Analysis Group III Cations 1. Prepare a complete flow chart fo...

A: Group 3 cation involve Cr3+ , Al3+ , Ni3+ and Fe3+ .

Q: One way to represent this equilibrium is: 2 Al(s) + 3 Br2(1)=2 AIBr3(s) We could also write this rea...

A: Characteristics of equilibrium constant (K) 1) if the reaction is reversed, the value of K is inver...

Q: HCI CH3-OH H20 (acid-catalyzed)

A: Given reactions are : Illustrate the carbocation pathway for the given reactions = ?

Q: 2. use oxidation number method

A: Balanced chemical reaction,

Q: Prelaboratory Assignment: Qualitative Analysis Group III Cations 1. Prepare a complete flow chart fo...

A: Group III cations are Fe3+, Al3+, Cr3+,Mn2+etc. the group reagent for analyzing group III cations ar...

Q: Consider the following reaction: cocCl2(g) co(g) + Cl2(g) If 9.25x10-3 moles of COCI,(g), 0.607 mole...

Q: When 0.615 g of sodium metal is added to an excess of hydrochloric acid, 6390 J of heat are produced...

Q: A 25.0 mL solution of acetic acid which is initially 1.0 mM CH3COO and 4.0 mM CH3COOH is titrated wi...

A: Given: Volume of solution = 25.0 mL = 0.025 L (Since 1 L = 1000 m...

Q: 3. At 105 °C, 0.5 mol of liquid water vaporizes into steam spontaneously because AS of the universe ...

A: Answer: Spontaneity of a process can be checked with the help of Gibbs free energy change. For a pro...

Q: How much lithium sulfite in grams, should be added to water to prepare a 627 mL of solution with a m...

A: Answer: Molecular formula of Lithium sulfite is: Li2SO3

Q: When 18.0 mL of a 5.43×104 M iron(II) nitrate solution is combined with 25.0 mL of a 7.60×10-4 M pot...

Q: What mass of phosphoric acid, H 3PO 4 Would actually react with 7.17 grams of LIOH? 3LIOH + H3PO4 → ...

Q: What volume in milliliters of 0.0180 M Sr(OH)2 is required to neutralize 65.0 mL of 0.0400 M HCI?

Q: The molecular structure of hinokitiol is represented below (See attached image) Draw a complete Lew...

Q: What problem(s) might occur if we make the following changes to the work-up procedure of our Ionone ...

A: The Ionone synthesis involves the reaction of citral and acetone in the presence of base catalyst to...

Q: Could you show me the carbocation pathway of CH3-OH? Tha

Q: Determine the polymers ABCD

A: Polymers are the organic molecules which are made up of the monomers (repeating units) that are cova...

Q: Complete the following table by calculating the missing entries and indicating whether the solutio i...

Q: An iron blast furnace produces pig iron of composition 94.2% Fe, 3.5% C, 1.5% Si, 0.8% burden of bla...

Q: Identify the suitable reagents for the following: H,O

Q: Create a timeline using illustrations and text showing on how elements form with the concept of atom...

A: Atomic no is basically how many protons are in the any element. In hydrogen there is 1 no of proton ...

Q: To produce a formate buffer solution that is at a pH of 4.06, what should the concentration of the f...

A: Buffer solution: The solution that resists the change in pH is known as a buffer solution. The buffe...

Q: 6) Write and balance this reaction: zinc sulfate plus strontium bromide yields, write out the produc...

Q: Consider the insoluble compound zinc sulfide, Zns. The zinc ion also forms a complex with hydroxide ...

A: Givens: Zn(OH)2-4 of Kf = 2.9×10 15 Find : Calculate the equilibrium constant ...

Q: The pKa values for the α-carboxylic acid and the α-amino acid groups is cysteine are 1.092 and 10.78...

Q: Use the molecular orbital model to fully describe the bonding in O2+, O2, O2-, and O22-. Determine w...

Q: Which of the below figures best represents what happens when MeINOs is added to water NO, Mg NO, Mg ...

A: Given: Mg(NO3)2 is added in water.

Q: What is the blanced chemical equation for. HNO3 + AgNO3 + K2003

A: Given incomplete reaction is : HNO3 + AgNO3 + K2CO3 --------------> ? Complete this reaction

Q: *Conclusion: Use complete sentences to answer each of the following: 1. What purpose did the cobalt ...

Q: ed by treatment with NH,OH. The colored prec H,OH to this acidic solution produces only a Which are ...

Q: In

A: In a tabular format, enumerate 5 molecules where the following atoms are found in: O (sp3-hybridize...

Q: Q2) A: Draw the crystal atomic planes with following Miller indices. (110), (101), (011), (111), (22...

A: Miller Indices indicate crystal atomic planes.

Q: one pair has significantly fewer similarities in chemistry than the other two pairs: Ca& Zn, Sc & Ga...

A: A question based on introduction to chemistry that is to be accomplished.

Q: increasing the temperature of the reaction The equilibrium shifts in the direction of reactants. The...

A: Concept: Chatelier's principle or The Equilibrium Law: Le Chatelier's principle states that when a...

Q: 2) Write and balance this reaction: solid iron (III) oxide produces solid iron plus oxygen gas. Iden...

Q: 3. A pH electrode system is calibrated with standard buffer solutions, with the following voltages o...

A: Solution- Data Given- pH 4.01=111 mV, pH= 7.00 = -55 mV, pH 10.01= -215 mV.

Question

Para-substituted product was produced when phenol reacts with
cyclohexanecarbonyl bromide in the presence of AIB13.
-Br
Cyclohexanecarbonyl bromide
(i)
Outline the mechanism for this reaction.
(ii)
Draw the alternative substituted product formed.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Step by step

Solved in 3 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

General Physical Properties of Organic Compounds

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium with their conjugated , -unsaturated isomers. Propose a mechanism for this isomerization.
When cyclohexene is reacted with hydrobromic acid in acetic acid, the major product is bromocyclohexane. There is a small amount of cyclohexyl acetate formed. What is the mechanism that forms both compounds? What is the purification procedure that isolates both compounds?
(a) Draw the products (including stereoisomers) formed when 2methylhex-2-ene is treated with HBr in the presence of peroxides. (b) Draw the products (including stereoisomers) formed when (S)-2,4dimethylhex-2-ene is treated with HBr and peroxides under similar conditions.
An alkene is treated with OsO4 followed by H2O2. When the resulting diol is treated with HIO4, the only product obtained is an unsubstituted cyclic ketone with molecular formula C6H10O. What is the structure of the alkene?
(a) Draw two different enol tautomers of 2-methylcyclohexanone. (b) Draw two constitutional isomers that are not tautomers, but contain a C=C and an OH group. 2-methylcyclohexanone
1) Nucleophilic substitution reaction of alkyl halide is a process when nucleophile replace the leaving group of alkyl halide. Propose the mechanism and product(s) for the following substitution reaction.
Draw the major organic product obtained by reaction of benzoyl chloride with dimethylamine, (CH3)2NH.
When trans-2-chloro-1-cyclohexanol is treated with a base, cyclohexene oxide is the product. However, when cis-2-chloro-1-cyclohexanol is treated with a base, the product is cyclohexanone. Why doesn’t the cis isomer yield the oxide?
(a) What product(s) are formed when the E isomer of C6H5CH = CHC6H5 is treated with Br2, followed by one equivalent of KOH? Label the resulting alkene(s) as E or Z. (b) What product(s) are formed when the Z isomer of C6H5CH = CHC6H5 is subjected to the same reaction sequence? (c) How are the compounds in parts (a) and (b) related to each other?
A synthetic organic molecule, G, which contains both aldehyde and ether functional groups, is subjected to a series of reactions in a multi-step synthesis pathway. In the first step, G undergoes a Wittig reaction, leading to the formation of an alkene, H. Subsequently, H is treated with an ozone (O3) reagent followed by a reducing agent in an ozonolysis reaction, resulting in the formation of two different products, I and J. Considering the functional groups present in G and the nature of the reactions involved, what are the most probable structures or functional groups present in products I and J? A. I contains a carboxylic acid group, and J contains an aldehyde group. B. I contains a ketone group, and J contains an alcohol group. C. I and J both contain aldehyde groups. D. I contains an ester group, and J contains a ketone group. Don't use chat gpt.
Identify two alkenes that react with HBr to form 1-bromo-1-methylcyclohexane without undergoing a carbocation rearrangement.
Predict the product. Draw the structure(s) of the major organic product(s) formed in the following reactions. Please indicate stereochemistry if appropriate.