ou are to prepare 100. mL of an acetate buffer of pH 5.00 using 1.0 M acetic acid (CH3CO2H, also written as HC2H3O2) and solid sodium acetate (NaC2H3O2). To prepare for the investigation, complete the following calculations. The pKa for HC2H3O2 is 4.74.     The Henderson-Hasselbach equation is pH = pKa + log ([conjugate base]/[acid])    (a) What ratio of [NaC2H3O2] to [CH3CO2H] is required for a pH = 5.00?   (b) You will want the concentrations relatively dilute, so use an acid concentration of 0.10 M. What volume of 1.0 M CH3CO2H would be needed to prepare 100. mL of buffer with the desired concentration of 0.10 M? Use M1V1 = M2V2  (c) Use the ratio from (a) and the concentration desired (discussed in (b)) to calculate how many grams of NaC2H3O2 · 3 H2O would be needed to prepare 100. mL of buffer if the acid concentration is 0.10 M?

Chemistry: Principles and Reactions
8th Edition
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Author:William L. Masterton, Cecile N. Hurley
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Chapter14: Equilibria In Acid-base Solutions
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You are to prepare 100. mL of an acetate buffer of pH 5.00 using 1.0 M acetic acid (CH3CO2H, also written as HC2H3O2) and solid sodium acetate (NaC2H3O2). To prepare for the investigation, complete the following calculations.

The pKa for HC2H3O2 is 4.74.  
 
The Henderson-Hasselbach equation is pH = pKa + log ([conjugate base]/[acid]) 
 
(a) What ratio of [NaC2H3O2] to [CH3CO2H] is required for a pH = 5.00?  
(b) You will want the concentrations relatively dilute, so use an acid concentration of 0.10 M. What volume of 1.0 M CH3CO2H would be needed to prepare 100. mL of buffer with the desired concentration of 0.10 M? Use M1V1 = M2V2 
(c) Use the ratio from (a) and the concentration desired (discussed in (b)) to calculate how many grams of NaC2H3O2 · 3 H2O would be needed to prepare 100. mL of buffer if the acid concentration is 0.10 M?  

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