||| O ORGANIC FUNCTIONAL GROUPS Predicting the products of symmetric alcohol dehydration Predict the missing product of this organic reaction: H+ OH + H₂O www-awu.alek Specifically, in the drawing area below draw the skeletal ("line") structure of P. Click and drag to start drawing a structure.
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- esc 1 O PRINCIPLES OF ORGANIC CHEMISTRY Classifying organic reactions The following chemical equation is for an elimination reaction, where the important atoms, groups, and bonds involved have been highlighted for you: Explanation O. -H 2 Use the information provided to predict the missing organic product and draw its structure in the drawing area below. Make sure to use the same skeletal ("line") style for the structure as the rest of the equation. Check H* Click and drag to start drawing a structure. w # 3 Q + H-0 $ 4 % 5 6 MacBook Pro & 7 Draw or edit atoms, groups, or bonds X C * 00 2/5 Cx 8 + Kimberly V © 2023 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility ? olo Ar + 1 HAR1. Refer to the dehydration reaction given below involving 2-butanol and answer the questions that follow. OH H,SO, CH;-CH,-CH-CH3 R + S i) The boiling point of 2-butanol is higher than butane. Give a reason for the difference in the boiling points of the two compounds. ii) The dehydration of 2-butanol yields two products R and S. Write the structure of the two products formed. Identify the major product. Explain the reason for your choice of the major product. 2. Indicate which is the stronger acid. Explain your choice clearly. H3C-CH-CH2 OH H3C-CH2 CH2OH or F 3. Give the IUPAC names of molecules CH3 H3C-CH-CH2 CH-CH-CH3 Br 4. A student was asked to prepare an alkene X in high yield using any alcohol as starting material CH3 CH;-C- -CH=CH2 CH3 X He chose 3, 3-dimethylbutan-2-ol (XI) and carried out a dehydration reaction. He was however horrified to note that the only alkene obtained was XII. CH3 ОН CH3 conc. H,SO4 CH-CH3 CH;-C=C-CH3 heat CH3 CH3 XI XII i) Explain what went wrong…HgSO4 H2SO4, H20 1T (1) Br H2O2, NaOH 10 NaNH2 BH3, THE H =H 1S NH3 H20 HCI (1 equiv.) diethyl ether 1V 1W Br2 (m) MgBr (H,C=CH),CULI NaOCI ТСРВА > 1X 1Y > 1Z CH3COOH 1AA diethyl ether SoCI2, pyridine diethyl ether 1AB
- Search Animations Slide Show Review View Help A Viewing E Share A A =、而 ... halle Identify primary / secondary / tertiary alcohols HO OH но R, R, R-C-OH Ri С-ОН H 10 primary alcohol 20 secondary alcohol 30 tertiary alcohol Help Improve Office A Notes 19 nols.pptx -. ho pause break scroll 16 f8 F9 f1o F11 f12Reset Help CH3 H3C-CH-CH3 H2N-CH2-CH3 H3C-CH2 OH H3C-C-CH2–CH3 Hydrocarbon Other organic compound G Search or type URL %23 & 4 5 6. 8 E R Y OP G H. C 2.D21 Discussion 2 - Public Speaking Sec... = O ORGANIC FUNCTIONAL GROUPS Predicting the products of symmetric alcohol dehydration Predict the missing product of this organic reaction: OH Explanation H tv A ALEKS-Jacari Johnson - Learn P + H₂O Specifically, in the drawing area below draw the skeletal ("line") structure of P. Check www-awu.aleks.com Click and drag to start drawing a structure. NA P C 2₁ x ċ Chem21Labs - online S Sun Fel 0/5 C Ć 2+ © 2023 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Ac
- PRELABORATORY QUESTIONS 1. Consider the following aldehydes and ketones, which you will study in today's experiment. CH3 CH2" | CHg-Ċ–CH3 CH2- CH=CH-C-H -CH2 Cinnamaldehyde Camphor CH3O. .C-H CH3-C-C-CH3 HO Varlin Dlacetyl (2,3-butanedlone) a. Which of the compounds are aldehydes? Which are ketones? b. Which of the aldehydes are aliphatic? Which are aromatic? c. Which compounds would react with Fehling's reagent? With Tollens' reagent? Write equations for all reactions that occur. d. Draw the structural formula of an acetal, formed from one of the aldehydes (your choice), ethyl alcohol, and a trace of acid. e. Which of the compounds would give a positive iodoform test? Write equations for reactions that occur. 2. Draw the structure of the functional for a hemiacetal. group 3. What is evidence for a positive Fehling's test? For a positive Tollens' test?CrO3 CH3CH2CH2OH CH3CH2COH CH3CH2COCH2CH2CH3 A problem often encountered in the oxidation of primary alcohols is that esters are sometimes produced as by-products. For example, oxidation of propyl alcohol yields propanoic acid and propyl propanoate. Draw curved arrows to show the movement of electrons in this step of the reaction mechanism. Arrow-pushing Instructions B: :0: CH3CH2CH- A: BH* CH;CH,CH нӧ: HÖ H-AH Br. H₂CH₂C H H Br t-BuOK t-BuOH "Br CH3 H NaCN DMF CH₂CH3 (CH3)3CO
- O HYDROCARBONS Predicting the reactants or products of alkene hydrogenation ive one possibility for the mystery reactant R in this organic reaction: R + H₂ Pd CH3 CH2 - CH2 - CH3 - Specifically, in the drawing area below draw the condensed structure of what R might be. There Note: keep in mind that the equation above states R and H₂ are present in a 1:1 mole ratio. Click anywhere to draw the first YE C XJSmol JSmol JSmol Methanol - CH3OH Ethanol - CH3CH2OH Propan-1-ol - CH3CH2CH2OH View/build molecular models (link in Moodle) of methanol (CH3OH), ethanol (CH3CH2OH), and propan-1-ol (CH3CH2CH2OH). What do you notice about the relative sizes of these molecules? How would this affect the intermolecular forces in these substances?Match the letters with the correct reagents می ملکی معیلی مله مه **All numerical values in answers should be subscript** a b C d e f g HO a OH Br, b ✓ [Choose ] DMP [Choose] 1. PhMgBr 2. H2O 1. MeMgBr 2.H2O 1. TsCl, base 2. tBuOH 1. BH3:THF 2. NaOH, H2O2 PBr3 1. Mg, O=C, H2O [ Choose ] [Choose ] OH [Choose ] OH