One of the factors that can affect the pH of a buffered solution is the molar ratio of the conjugate base and weak acid. Which of the following statement is correct?     "If the concentration of the conjugate base is higher than the weak acid, the pH will be less than the pKa."     "If the concentration of the conjugate base is less than the weak acid, the pH will be less than the pKa."     "If the concentration of the conjugate base is higher than the weak acid, the net change of the pH is going to the acidic side (lower pH)"     "If the concentration of the conjugate base is less than the weak acid, the net change of the pH is going to the basic side (higher pH)"

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Chapter1: Chemical Foundations
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One of the factors that can affect the pH of a buffered solution is the molar ratio of the conjugate base and weak acid. Which of the following statement is correct?
   
"If the concentration of the conjugate base is higher than the weak acid, the pH will be less than the pKa."
   
"If the concentration of the conjugate base is less than the weak acid, the pH will be less than the pKa."
   
"If the concentration of the conjugate base is higher than the weak acid, the net change of the pH is going to the acidic side (lower pH)"
   
"If the concentration of the conjugate base is less than the weak acid, the net change of the pH is going to the basic side (higher pH)"
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