N02 Nitration conc. HNO3+ conc H2Sou Bentene NitHobenzene Mechanism:- Nittoanium ion NO2 + 0=N=0 → -NO2 quoup is meta directing guoup tep3 * Synthesis of Phenol fHom benzene:- ONa Chlosination

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
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Chapter17: Alcohols And Phenols
Section17.SE: Something Extra
Problem 60AP: Benzvl chloride can be converted into benzaldehvde by treatment with nitromethane and base. The...
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12:44
* Synthesis ot hitiobenzene fom benzene:-
NO2
Nitration
Conc. HNO3+
conc H2Sou
Benzene
Nitiobenzene
Mechanism:-
2 0=Ñ= o t HzO
Nittoanium
ion
NO2
+ 0=N=0 →
)-NO2 quoup is meta directing guoup
Step3
c)
* Synthesis of Phenol feom benzene:-
ONa
Chlosination
C12
- HCI
Feci3
Sodium
phenoxide
Benzene
Chlosio benzene
Ht
HCI
- NaCI
Phenol
n) -OH gyoup is oatho-para dinecting guoup.
?
Transcribed Image Text:12:44 * Synthesis ot hitiobenzene fom benzene:- NO2 Nitration Conc. HNO3+ conc H2Sou Benzene Nitiobenzene Mechanism:- 2 0=Ñ= o t HzO Nittoanium ion NO2 + 0=N=0 → )-NO2 quoup is meta directing guoup Step3 c) * Synthesis of Phenol feom benzene:- ONa Chlosination C12 - HCI Feci3 Sodium phenoxide Benzene Chlosio benzene Ht HCI - NaCI Phenol n) -OH gyoup is oatho-para dinecting guoup. ?
of the molemles from the phato and draw
a dedalled
Pick a synthetic route to one
pushing
a proposed syntheses.(ie. you only need to show the mechanism
arow
mechanism CS) to erplein al
Steps
for one
of the propsed syntheses of the disubsdituted benzene mole.cmles )
Transcribed Image Text:of the molemles from the phato and draw a dedalled Pick a synthetic route to one pushing a proposed syntheses.(ie. you only need to show the mechanism arow mechanism CS) to erplein al Steps for one of the propsed syntheses of the disubsdituted benzene mole.cmles )
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