Monosaccharides are cyclic hemiacetals that can react with alcohols to form acetals. The bond between the anomeric carbon atom of the monosaccharide and the oxygen atom of the -OR group is called a glycosidic bond. The name of the linkage contains the designation alpha (a) or beta (B) (from the anomeric carbon in the glycosidic bond) and the carbon numbers for the carbons from the two sugars. For this example, the linkage is an a-1,4 glycosidic bond. HO OH H HO ن H ات انتساب OH H OH CH2OH - + a anomer HO - Classify the glycosidic linkage in the disaccharide. -0 H OH HC H OH H H OH H OH OH OH - HO HO H OH CH2OH OH -OH H OH ت an a glycosidic bond + 0 O O B-1,6 a-1,6 a-1,1 B-15 I DON'T KNOW YET submit

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter25: Carbohydrates
Section: Chapter Questions
Problem 25.39P
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Monosaccharides are cyclic hemiacetals that can react with alcohols to form acetals. The bond between the
anomeric carbon atom of the monosaccharide and the oxygen atom of the -OR group is called a glycosidic bond. The
name of the linkage contains the designation alpha (a) or beta (B) (from the anomeric carbon in the glycosidic bond)
and the carbon numbers for the carbons from the two sugars. For this example, the linkage is an a-1,4 glycosidic
bond.
Н
НО
HO
اب تاب است
H
OH
H
OH
-OH
Н
Н
OH
H
+
OH HO
a anomer
CH₂OH
H
Н
H
О
OH H2C
OH
Н
H
Classify the glycosidic linkage in the disaccharide.
Н
OH
Н
H
OH
OH
OH
-
HO
Н
H
HO
OH
OH
Н
CH₂OH
H
-OH
H
OH
он
H
H
-OH
Н
OH
an a glycosidic bond
Н
OH
+ H2O
о
о
о
о
В-1,6
a-1,6
a-1,1
B-1,5
I DON'T KNOW YET
submit
Transcribed Image Text:Monosaccharides are cyclic hemiacetals that can react with alcohols to form acetals. The bond between the anomeric carbon atom of the monosaccharide and the oxygen atom of the -OR group is called a glycosidic bond. The name of the linkage contains the designation alpha (a) or beta (B) (from the anomeric carbon in the glycosidic bond) and the carbon numbers for the carbons from the two sugars. For this example, the linkage is an a-1,4 glycosidic bond. Н НО HO اب تاب است H OH H OH -OH Н Н OH H + OH HO a anomer CH₂OH H Н H О OH H2C OH Н H Classify the glycosidic linkage in the disaccharide. Н OH Н H OH OH OH - HO Н H HO OH OH Н CH₂OH H -OH H OH он H H -OH Н OH an a glycosidic bond Н OH + H2O о о о о В-1,6 a-1,6 a-1,1 B-1,5 I DON'T KNOW YET submit
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