Modify the given copies of the starting materials to draw the major product(s) for the following Diels-Alder reaction. Use the single bond tool to interconvert between double and single bonds, and use wedges and dashes to indicate the stereochemistry of any newly formed chiral centers. If a pair of enantiomers is expected, be sure to draw both enantiomers. Note: you can save time drawing by selecting a structure and using the copy/paste function. + CH₂ CH₂ Edit Drawing CO

Modify the given copies of the starting materials to draw the major product(s) for the following Diels-Alder reaction. Use the single bond tool to interconvert between double and single bonds, and use wedges and dashes to indicate the stereochemistry of any newly formed chiral centers. If a pair of enantiomers is expected, be sure to draw both enantiomers. Note: you can save time drawing by selecting a structure and using the copy/paste function. + CH₂ CH₂ Edit Drawing CO

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter8: Addition Via Carbocation

Section: Chapter Questions

Problem 9E

See similar textbooks

Similar questions

How do you draw the diels-alder product for this with stereochemistry? How do you know they are cis?
Click the "draw structure" button to launch the drawing utility. Draw the diene and dienophile that are needed to prepare the following Diels-Alder product. Diene: Dienophile: draw structure ... draw structure ...
] Draw the structure of Diels-Alder cycloadduct formed via an endo 3. [a, transition state structure involving the diene and dienophile shown here. [b Formulate the endo transition structure that leads to the product. [c is observed. Does it correspond to a primary or a secondary KIE? Explain. [d. the 'inverse' variety? Explain. -CO2ET ]A KIE ] Is the KIE of the 'normal' or
10. The following compound was produced in a Diels-Alder reaction. COOH a) How many sp³ hybridized carbons are in this molecule? b) Is this molecule chiral? c) Are the carboxylic acid substituents electron donating group or electron withdrawing group? d) Draw the diene and dienophile which would react together to give this product.
This Diels-Alder reaction prodoces a rmcamic producr mixnare. In the box below draw the stracture of one of these stereoisomers. • Lae Ibe wodgerhash beod tools to indicate stereochemistry where it cxista. • Include Hatoma at chiral centers only. • Ila group is achiral, du not use wedyed or hashed bunds en il
Which of the following compounds can arise directly from a Diels-Alder reaction? Circle any structures that can. Then, identify the appropriate diene(s) and dienophile(s) that would lead to the compound. Pay attention to E-/Z- stereochemistry in all of the reactants. For those that cannot undergo a Diels-Alder reaction, please explain why.
This is a Diels-Alder reaction between cyclopentadiene and maleic anhydride (endo and exo products). For each cycloaddition product, draw in all hydrogen atoms, and write the molecular formula below.
This is a Diels-Alder reaction between furan + maleic anhydride (endo and exo products). For each cycloaddition product, draw in all hydrogen atoms, and write the molecular formula below.
b.) Draw the major product for the following reaction. heat c.) Please draw the anticipated product from this Diels-Alder reaction. Hint: anthracene's middle phenyl ring contains a reactive diene. CO2ME MeO2C heat 3.) For the following intermediates, please draw as many resonance contributors that you can come up with. Then circle the highest contributor and draw a hybrid resonance illustration for each molecule. 2
Draw a structural formula for the product of this Diels-Alder reaction, including all stereoisomers of the product. &.I- CHO ● CHO • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If a group is achiral, do not use wedged or hashed bonds on it. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu.
Imagine that you used isoprene as diene – in that case you don’t have to worry about assigning endo vs exo. Draw the "endo" and "exo" products of the Diels-Alder reaction between isoprene and maleic anhydride, and explain why the distinction is irrelevant here.
I know the product and the arrow pushing for both reactions, but I need assistance with the FMO energy diagrams. I know the first one is a normal Diels alder reaction and the second one is Inverse electron demand Diels–Alder reaction. But, I am confused about how to draw them out.