Le Châtelier’s principle is related ultimately to the rates ofthe forward and reverse steps in a reaction. Explain (a) why anincrease in reactant concentration shifts the equilibrium positionto the right but does not change K; (b) why a decrease in Vshiftsthe equilibrium position toward fewer moles of gas but does notchange K; (c) why a rise in Tshifts the equilibrium position of anexothermic reaction toward reactants and also changes K;and(d) why a rise in temperature of an endothermic reaction from T1to T₂ results in K₂ being larger than K1
Le Châtelier’s principle is related ultimately to the rates ofthe forward and reverse steps in a reaction. Explain (a) why anincrease in reactant concentration shifts the equilibrium positionto the right but does not change K; (b) why a decrease in Vshiftsthe equilibrium position toward fewer moles of gas but does notchange K; (c) why a rise in Tshifts the equilibrium position of anexothermic reaction toward reactants and also changes K;and(d) why a rise in temperature of an endothermic reaction from T1to T₂ results in K₂ being larger than K1
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.81P
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Le Châtelier’s principle is related ultimately to the rates ofthe forward and reverse steps in a reaction. Explain (a) why anincrease in reactant concentration shifts the equilibrium positionto the right but does not change K; (b) why a decrease in Vshiftsthe equilibrium position toward fewer moles of gas but does notchange K; (c) why a rise in Tshifts the equilibrium position of anexothermic reaction toward reactants and also changes K;and(d) why a rise in temperature of an endothermic reaction from T1to T₂ results in K₂ being larger than K1
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