Label the areas of the curve where a buffer is present. Locate the point where pH= pKa (halfway to the equivalence point.) Label pKa on the graph. If the acid is polyprotic, label the pKa for each equivalence point on the graph. pKal = pK₁2 = Kal Calculate Ka for your unknown acid. f your unknown is polyprotic, calculate Ka at both the equivalence points. (Show work) (from the graph) K₁2 =

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Chapter7: Solutions And Colloids
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Problem 7.108E
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Data Sheet:
Unknown acid #9
Mass of the Unknown acid:
Volume NaOH added
0.5 ml
TWST
2.0ml
2.5ml
(letter or number on the unknown bottle)
Concentration of NaOH(aq):
#2
30ml
3.5mi
40ml
4.5ml
3.0ml
Twiss
6.0m)
6.SMI
1.0m)
TWIST
80ml
8.5ml
9.0ml
9.9ml
100ml
10.5ml
11.0m
11.5m
12.0ml
12,5 ml
13.0 ml
B.S ml
14.0 ml
14.5 ml
15.0 ml
21
0.209
PH
364 3.26
369 3:24
3:26
3:28
3.28
3:30
3:35
3:44
t
3,39
2.93
9.91
351
3.54
3.58
3.64
3.72
3.80
3.867
3.93
$4.00
4.061
4:13.
4 4.20
4.28
4.35
4.43
4.46
4.64
4.83
5.05
Volume NaOH added
15.5ml
16.0 ml
16.5ml
17.0ml
17.5ml
0.0995M
pH
10.63
10:03
11.25
11.37
11.50
Transcribed Image Text:Data Sheet: Unknown acid #9 Mass of the Unknown acid: Volume NaOH added 0.5 ml TWST 2.0ml 2.5ml (letter or number on the unknown bottle) Concentration of NaOH(aq): #2 30ml 3.5mi 40ml 4.5ml 3.0ml Twiss 6.0m) 6.SMI 1.0m) TWIST 80ml 8.5ml 9.0ml 9.9ml 100ml 10.5ml 11.0m 11.5m 12.0ml 12,5 ml 13.0 ml B.S ml 14.0 ml 14.5 ml 15.0 ml 21 0.209 PH 364 3.26 369 3:24 3:26 3:28 3.28 3:30 3:35 3:44 t 3,39 2.93 9.91 351 3.54 3.58 3.64 3.72 3.80 3.867 3.93 $4.00 4.061 4:13. 4 4.20 4.28 4.35 4.43 4.46 4.64 4.83 5.05 Volume NaOH added 15.5ml 16.0 ml 16.5ml 17.0ml 17.5ml 0.0995M pH 10.63 10:03 11.25 11.37 11.50
6. Label the areas of the curve where a buffer is present. Locate the point where pH= pKa (halfway to
the equivalence point.) Label pKa on the graph. If the acid is polyprotic, label the pK₁ for each
equivalence point on the graph.
pKal =
Kal=
pK₁2 =
7. Calculate Ka for your unknown acid. f your unknown is polyprotic, calculate Ka at both the equivalence
points. (Show work)
=
(from the graph)
K₁2 =
8. What is the identity of your unknown? Explain your reasoning behing your choice of unknown.
9. Calculate the initial concentration of your acid. Recall that the original volume of the solution was
0.100 L
[Acid] initial
Using your calculated value of K, and the initial concentration of the acid, calculate the initial pH of
your acid.
Set up the ICE table. You may need to use the quadratic formula.
Transcribed Image Text:6. Label the areas of the curve where a buffer is present. Locate the point where pH= pKa (halfway to the equivalence point.) Label pKa on the graph. If the acid is polyprotic, label the pK₁ for each equivalence point on the graph. pKal = Kal= pK₁2 = 7. Calculate Ka for your unknown acid. f your unknown is polyprotic, calculate Ka at both the equivalence points. (Show work) = (from the graph) K₁2 = 8. What is the identity of your unknown? Explain your reasoning behing your choice of unknown. 9. Calculate the initial concentration of your acid. Recall that the original volume of the solution was 0.100 L [Acid] initial Using your calculated value of K, and the initial concentration of the acid, calculate the initial pH of your acid. Set up the ICE table. You may need to use the quadratic formula.
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