In the early age of the development of Organometallilc Chemistry, the preparation of Organometallic Compound containing M-R(R: alkyl group) bond always led to the decomposition of the M-R bond. It was later known to be caused by the so called “beta-hydrogen elimination” process. Which of the following statements is not correct?This process can be prevented by using all halogenated alkyl group.This process can be prevented by carrying out reaction at high temperature.The Grignard’s reagent, RMgX or R2Mg is stable and does not undergo “b-hydrogen elimination” process.The anti-knocking agent, Pb(C2H5)4 is stable and does not undergo “b-hydrogen elimination” process.The ferrocene, Cp2Fe, is free from the “b-hydrogen elimination” process.

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Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions

Section19.SE: Something Extra

Problem 29VC

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In the early age of the development of Organometallilc Chemistry, the preparation of Organometallic Compound containing M-R(R: alkyl group) bond always led to the decomposition of the M-R bond. It was later known to be caused by the so called “beta-hydrogen elimination” process. Which of the following statements is not correct?

This process can be prevented by using all halogenated alkyl group.
This process can be prevented by carrying out reaction at high temperature.
The Grignard’s reagent, RMgX or R₂Mg is stable and does not undergo “b-hydrogen elimination” process.
The anti-knocking agent, Pb(C₂H₅)₄ is stable and does not undergo “b-hydrogen elimination” process.
The ferrocene, Cp₂Fe, is free from the “b-hydrogen elimination” process.

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