In the conversion of benzaldehyde to benzoin exp. Cyanide ion was used as catalyst in such condensation reaction, for many properties. One of the following properties is False: a. Cyanide ion readily adds to carbonyl group of aldehyde b. It could catalyze proton transfer C. It is a good leaving group d. Cyanide group can stabilize the carbocation intermediate formed through resonance. In the oxidation of p-nitrotoluene to p- nitrobenzoic acid experiment, in order to remove the chromium salts from the crude acid product: a. Wash with 10% NaOH solution then by 5%H2SO4 solution b. Warm with 5% H2SO4 solution C. Heat with dilute NaOH d. Wash with 5% Na CO3 solution and then with 10% HCI solution

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter21: Benzene And The Concept Of Aromaticity
Section: Chapter Questions
Problem 21.58P
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In the conversion of benzaldehyde to
benzoin exp. Cyanide ion was used as
catalyst in such condensation reaction, for
many properties. One of the following
properties is False:
a. Cyanide ion readily adds to carbonyl
group of aldehyde
b.
It could catalyze proton transfer
C. It is a good leaving group
d. Cyanide group can stabilize the
carbocation intermediate formed
through resonance.
In the oxidation of p-nitrotoluene to p-
nitrobenzoic acid experiment, in order to
remove the chromium salts from the crude
acid product:
a.
Wash with 10% NaOH solution then
by 5%H,SO4 solution
b. Warm with 5% H2SO4 solution
C. Heat with dilute NaOH
d. Wash with 5% Na CO3 solution and
then with 10% HCI solution
Transcribed Image Text:In the conversion of benzaldehyde to benzoin exp. Cyanide ion was used as catalyst in such condensation reaction, for many properties. One of the following properties is False: a. Cyanide ion readily adds to carbonyl group of aldehyde b. It could catalyze proton transfer C. It is a good leaving group d. Cyanide group can stabilize the carbocation intermediate formed through resonance. In the oxidation of p-nitrotoluene to p- nitrobenzoic acid experiment, in order to remove the chromium salts from the crude acid product: a. Wash with 10% NaOH solution then by 5%H,SO4 solution b. Warm with 5% H2SO4 solution C. Heat with dilute NaOH d. Wash with 5% Na CO3 solution and then with 10% HCI solution
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