In a study of the gas phase decomposition of hydrogen iodide at 700 K HI(g) →½ H₂(g) + ½ I₂(g) the concentration of HI was followed as a function of time. It was found that a graph of 1/[HI] versus time in seconds gave a straight line with a slope of 1.64x10-³ M-¹ s-¹ and a y-intercept of 0.418 M-¹. Based on this plot, the reaction is order in HI and the rate constant for the reaction is M-¹ S-¹.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.1: Reaction Rate
Problem 11.3CE
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In a study of the gas phase decomposition of hydrogen iodide at 700 K
HI(g)- → H₂(g) + ½ I₂(g)
the concentration of HI was followed as a function of time.
It was found that a graph of 1/[HI] versus time in seconds gave a
straight line with a slope of 1.64×10-³ M-¹ s-¹ and a y-intercept of
0.418 M-¹.
Based on this plot, the reaction is
order in HI and the rate
constant for the reaction is
M-¹ S-¹.
Transcribed Image Text:In a study of the gas phase decomposition of hydrogen iodide at 700 K HI(g)- → H₂(g) + ½ I₂(g) the concentration of HI was followed as a function of time. It was found that a graph of 1/[HI] versus time in seconds gave a straight line with a slope of 1.64×10-³ M-¹ s-¹ and a y-intercept of 0.418 M-¹. Based on this plot, the reaction is order in HI and the rate constant for the reaction is M-¹ S-¹.
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