Identify the MAJOR product(s) that would be obtained from the following TWO-STEP reaction sequence. 1) Br2 (1 equiv) 2) Cl2 Nal (excess) CI Br (+ enantiomer) Br Br Br Br CI
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- What is(are) the major final product(s) formed during the following sequence of reactions? 01 11 V 1.0₂ 2. (CH₂)₂S C₂H₂O 2 identical molecules ||| =PPhy < IV орна6. Complete reaction scheme below indicating reagents, catalysts and conditions, and side product trigil bezinslog si6101fon 290b 1l (b Senines levirba 6 gaubong nasamots gniwollot ads to doinW 01 sniowl (6 CH3 40 CH3 Scansgowi (d Ege nodie) ( nsgyxo (b NO₂ 19m02 2i gniwollet sits to mainW II HOWhich conditions will produce the target product in the highest yield? O A) 1. BH3; 2. H₂O₂, NaOH, H₂O B) 1. OsO; 2. S(CH3)2 C) 1. Hg(OAc)₂, H₂O; 2. NaBH4 D) H₂SO4, H₂O A ? B OH racemic mixture
- Which synthetic route(s) would complete the reaction shown? Br || ||| I and II O I and III ? HO OH + enantiomer Synthesis I: 1. NaCCCH3; 2. Na/NH3(I) ;3. OsO4; 4. NaHSO3, H₂O Synthesis II: 2. NaCCCH3; 2. H2, Lindlar's catalyst; 3. MCPBA; 4. aq. H₂SO4 Synthesis III: 1. NaCCCH3; 2. H₂, Pt; 3. MCPBA; 4. aq. H₂SO4Steps 'H. Which reaction steps would you use to carry out the synthesis shown? phenylacetylene 1. Na/NH3; CH3CH2Br 1. Hвr 2. (C2H5)2CULI 1. HBr 2. NaNH2; CHЗCH2Br 1. NaNH2; CH3CH2Br 2. LI/NH3What is the expected major product for the following reaction? O IV I OCH 3 |||||... + enantiomer || 1. Hg(OAc)2, CH3OH 2. NaBH4 НО. OH ... H3CO. + enantiomer ||| IV H3CO V
- 2. Draw the products for the following reaction conditions using the starting material provided. 1. CH3LI; 2. H20 of 1. CH3CH2MgBr 2.H20 1.(CH2CH),CuLi 2. H20can you explain how can we determine major and minor product from these reaction elimination-addition? &=&=1561=6, NH₂ majo CH, NH₂ NH₂ &=-&-&-& majo CH3 OCH, CI NINH, NH 3liq. KNH₂ NH309. Br ΚΝΗ, NH CI CH₁ 80 80 OCH, majo NH, NH₂ mino CH3 mino NH₂ NH₂ NH, NH, CI majo CH3 majo NH₂ NH₂intermediates/products for this reaction Supply the missing . Please Show all 24.49. arrow pushimed Méchansmsi Mg(s). 1.8 Br2 Na,Cr,0z H2SO, SOCI, A B FeBr3 2. H300 AICI, Thanto ga! OCH3 Conc. H3PO4 → G OCH3 H. NABH4. ELOH A
- c. Snl reactions dominate under polar protic solvents. Increasing the polarity of the solvent will increase the rate of the reaction because the polar solvent will stabilize the dispersed charges on the transition state more than it will stabilize the neutral reactant. Label areas of ô* and & on the molecules of the transition state of the SN1 reaction below: Me Me Ме Me Me H20 Br -Br OH + НО \'H Et Et RDS Et H Et Et transition state not isolable carbocation intermediate not isolable6). What is the major product of the following reactions? (A) -? coon 1). NaOH in ErOH, then H,O+ 2). 1 eqiv. NaOEt 3). 1 equiv. CH3Br 4). H₂O*, Heat COOB (Intramolecular Claison) COOE (B) CH₂ COOH (D) CH₂ (E) CH3 CH₂Identify compounds A-I in the following synthesis scheme. CUCN D conc HNO3 1. HCI, Fe NaNO2 A 2. NaOH В HCI Same as above Br2 Mg(s). F Et,0 1. D NaBH4 1. NaH >E FeBr3 G ELOH 2. H2О (еxcess), H,SO4 2. C6H5CH,Br