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Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter6: Types Of Chemical Reactions And Solution Stoichiometry
Section: Chapter Questions
Problem 43E
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173
10
Temperature 20,3°C * Rate is dependent 6A EP
Run
[]o
Rate (A[I2]/At)
k
[S,O ]o
[S2O;? ]o
A [L2]
At
Units:
m
m/s
m
Sec
Dilution Eg
1
0.0800 m
0.0400 m
0.00100 m 5.00 x 104
0.0800 m
0.00100m
92.0s
0.0800 m
60.0s
3.
0.00100m
4.
0.0400 m
0.00100 m
82.0s
56.0 s
0.0400 m 0.00100 m
(0.200 m)(20.0mL) (0.100m)( 20.00mL) Co.00S Dom)(10.0ml) AU,]= ½[$,0],
Transcribed Image Text:173 10 Temperature 20,3°C * Rate is dependent 6A EP Run []o Rate (A[I2]/At) k [S,O ]o [S2O;? ]o A [L2] At Units: m m/s m Sec Dilution Eg 1 0.0800 m 0.0400 m 0.00100 m 5.00 x 104 0.0800 m 0.00100m 92.0s 0.0800 m 60.0s 3. 0.00100m 4. 0.0400 m 0.00100 m 82.0s 56.0 s 0.0400 m 0.00100 m (0.200 m)(20.0mL) (0.100m)( 20.00mL) Co.00S Dom)(10.0ml) AU,]= ½[$,0],
Solutions for Kinetic Runs
Run
Flask A
Flask B
250 mL beaker
1
20.00 mL 0.200 M KI
10.00 mL 0.00500 M Na2S2O3
5 drops starch
20.00 mL 0.100 M K2S2O8
10.00 mL 0.100 M K2S2O8
10.00 mL 0.100 M NazSO4
20.00 mL 0.200 M KI
10.00 mL 0.00500 M Na2S2O3
5 drops starch
15.00 mL 0.100 M K2S2O8
5.00 mL 0.100 M Na2SO4
20.00 mL 0.200 M KI
10.00 mL 0.00500 M Na2S2O3
5 drops starch
10.00 mL 0.200 M KI
10.00 mL 0.00500 M Na2S20
5 drops starch
4.
20.00 mL 0.100 M K2S2O8
10.00 mL 0.200 KCI
15.00 mL 0.200 M KI
20.00 mL 0.100 M K2S2O8
10.00 mL 0.00500 M Na2S2O
5.00 mL 0.200 M KCI
5 drops starch
For each of the above, measure the KI and the K2S2O8 precisely from the burets. The
KCl and NazSO, solutions are added only to keep the total ionic concentration in each
mixture the same. This is necessary to avoid secondary effects.
1. Calculate the initial concentrations of I, S20g, and S203 in each run using the data
in Table 12.2 and the dilution formula M¡V1 M2V2, is as follows:
2-
2-
%3D
(0.200 M)(20.00 mL)
[r]o=
=0.0800 M
(50.00 mL)
(0.100 M)(20.00 mL)
[S,0, 1,=
%3D
30.0400 M
(50.00 mL)
(0.00500 M)(10.00 mL)
[s,0,*1,-
%30.00100 M
%3D
(50.00mL)
2.
3.
Transcribed Image Text:Solutions for Kinetic Runs Run Flask A Flask B 250 mL beaker 1 20.00 mL 0.200 M KI 10.00 mL 0.00500 M Na2S2O3 5 drops starch 20.00 mL 0.100 M K2S2O8 10.00 mL 0.100 M K2S2O8 10.00 mL 0.100 M NazSO4 20.00 mL 0.200 M KI 10.00 mL 0.00500 M Na2S2O3 5 drops starch 15.00 mL 0.100 M K2S2O8 5.00 mL 0.100 M Na2SO4 20.00 mL 0.200 M KI 10.00 mL 0.00500 M Na2S2O3 5 drops starch 10.00 mL 0.200 M KI 10.00 mL 0.00500 M Na2S20 5 drops starch 4. 20.00 mL 0.100 M K2S2O8 10.00 mL 0.200 KCI 15.00 mL 0.200 M KI 20.00 mL 0.100 M K2S2O8 10.00 mL 0.00500 M Na2S2O 5.00 mL 0.200 M KCI 5 drops starch For each of the above, measure the KI and the K2S2O8 precisely from the burets. The KCl and NazSO, solutions are added only to keep the total ionic concentration in each mixture the same. This is necessary to avoid secondary effects. 1. Calculate the initial concentrations of I, S20g, and S203 in each run using the data in Table 12.2 and the dilution formula M¡V1 M2V2, is as follows: 2- 2- %3D (0.200 M)(20.00 mL) [r]o= =0.0800 M (50.00 mL) (0.100 M)(20.00 mL) [S,0, 1,= %3D 30.0400 M (50.00 mL) (0.00500 M)(10.00 mL) [s,0,*1,- %30.00100 M %3D (50.00mL) 2. 3.
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