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- Question 18 of 25 Identify the equilibrium below that shows the two chair conformations of the following compound: 4 O H 1 Q A = Type here to search (@ # 2 W S 3 E D F3 $ 4 R FL % 5 T G <6 1 F6 Y PrtScn & H 7 F7 U Home 8 JWhat is the difference between a constitutional, confirgurational, and a conformational isomer?Perspective drawings of Chair and Boat Conformers fo Cyclohexane (C6H12). Note it is impossible to place all the carbons in the same plane without straining the bonds. Take two opposite carbons and pull both of them up to make one conformation adn then pull one of them down to make the other conformation. Can you inercovert one conformer int othe other without breaking any bonds? Explain why these represent conformers and not isomers.
- FO 23: Identify and draw conformers. NH₂ NH2 NH2 NH2 NH2 NH2 1 NH2 NH2 4 2 3 (a) List any two structures that are related as conformers. Answer by listing exactly two numbers. (b) Draw one conformer of the new structure shown here: 1 and 3 (b) OH HO OHConvert the following structure into a 3D model in the same conformation as shown below. After making the 3D model, click on the motorcycle to optimize the structure. The 3D model must be in the same conformation as the wedge-dash structure. Ex D Br XX D 3 3 []d) Molecular relationships; identify whether the compounds in each group are const. isomers, conformers, enantiomers, diastereomers, identical, meso or none of the above. ОН ОН H3C Br H3C LF H Br CH3 HO CI Br Br CI NH NH
- H H,C OH C2 C3 HO CH3 H Which of the following is the most stable staggered conformer? H. Me OH Me OH Me. OH Me. OH Me OH но H. Me H H Conformer A Conformer B Conformer C Conformer B because the anti OH groups avoid hydrogen bonding, which is a destabilizing effect. Conformer A because there are only two gauche interactions, and hydrogen bonding between the two OH groups is a stabilizing effect. Conformer C because there is no steric strain for Me-OH gauche interactions and hydrogen bonding between the two OH groups is a stabilizing effect. Conformer B because the large OH groups are anti to each other.Draw 2 isomenthol chair conformers. Include axial and equatorial groups. Explain which is more stable.Which of the following line drawings represents the correct stereochemistry o molecule shown in the Newman projection below? E + Н. H I CH₂CH3 LOH H CH3 OH OH || IV OH 5.... OH A) I B) II C) III D) IV K
- The correct relationship between the following pairs is CH3 H H H3C. H- CH2CH3 H. H3C H. Select one: o conformers O Not isomers constitutional isomers Identical cis-transCyclohexane structures can have two chair conformations. Draw the alternate conformation of the structure shown below. Rotations of the structure are not allowed. Br CI Flip HMatch the following pair of organic compounds with the specific type of isomerism that they exhibit. Match each item to a choice: H3C CH3 CH3 но -H H OH H -HO- но -H HO, HO. H3C H;C OH Choices: E Skeletal Isomers : Non-isomers : Geometric Isomers : Diastereomers : Functional Isomers : Enantiomers E Positional Isomers