Name:Relative Number of Electrons8. Given the photoelectron spectra below for phosphorus, P, and sulfur, S, which of the followingbest explains why the 2p peak for S is further to the left than the 2p peak for P, but the 3ppeak for S is further to the right than the 3p peak for P?Relative Number of Electrons1000100020823910010013518.716.522.710Due: Wed., 3/1/2310Binding Energy1.952.051.061.001PhosphorusP0.1 MJ/molSulfurSAP Chemistry6.1 MJ/mol(A) S has a greater effective nuclear charge than P, and the 3p sublevel in S has greater electronrepulsions than in P.(B) S has a greater effective nuclear charge than P, and the 3p sublevel is more heavily shieldedin S than in P.I(C) S has a greater number of electrons than P, so the third energy level is further from thenucleus in S than in P.(D) S has a greater number of electrons than P, so the Coulombic attraction between the electroncloud and the nucleus is greater in S than in P.

Photoelectron spectroscopy (PES) is an experimental technique used to determine the relative…

Given the photoelectron spectra below for phosphorus, P, and sulfur, S, which of the following best explains why the 2p peak for S is further to the left than the 2p peak for P, but the 3p peak for S is further to the right than the 3p peak for P? 135

Given the photoelectron spectra below for phosphorus, P, and sulfur, S, which of the following best explains why the 2p peak for S is further to the left than the 2p peak for P, but the 3p peak for S is further to the right than the 3p peak for P? 135

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter5: Electron Configurations And The Periodic Table

Section: Chapter Questions

Problem 139QRT

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Question

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Name:
Relative Number of Electrons
8. Given the photoelectron spectra below for phosphorus, P, and sulfur, S, which of the following
best explains why the 2p peak for S is further to the left than the 2p peak for P, but the 3p
peak for S is further to the right than the 3p peak for P?
Relative Number of Electrons
1000
1000
208
239
100
100
135
18.7
16.5
22.7
10
Due: Wed., 3/1/23
10
Binding Energy
1.95
2.05
1.06
1.00
1
Phosphorus
P
0.1 MJ/mol
Sulfur
S
AP Chemistry
6.1 MJ/mol
(A) S has a greater effective nuclear charge than P, and the 3p sublevel in S has greater electron
repulsions than in P.
(B) S has a greater effective nuclear charge than P, and the 3p sublevel is more heavily shielded
in S than in P.
I
(C) S has a greater number of electrons than P, so the third energy level is further from the
nucleus in S than in P.
(D) S has a greater number of electrons than P, so the Coulombic attraction between the electron
cloud and the nucleus is greater in S than in P.

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