form a simple cubic unit cell 1. The anions of CsCl fill the octahedral holes 2. The anions NaCl and ZnS form a body-centered cubic unit cell 3. The cations of CsCI fill the tetrahedral holes 4. The cations of NaCl fill the cubic holes form a face-centered cubic unit cell 5. The cations of ZnS fill every other tetrahedral hole

form a simple cubic unit cell 1. The anions of CsCl fill the octahedral holes 2. The anions NaCl and ZnS form a body-centered cubic unit cell 3. The cations of CsCI fill the tetrahedral holes 4. The cations of NaCl fill the cubic holes form a face-centered cubic unit cell 5. The cations of ZnS fill every other tetrahedral hole

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter9: Liquids And Solids

Section: Chapter Questions

Problem 53QAP: In the LiCl structure shown in Figure 9.21, the chloride ions form a face-centered cubic unit cell...

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What is a lattice? What is a unit cell? Describe a simple cubic unit cell. How many net atoms are contained in a simple cubic unit cell? How is the radius of the atom related to the cube edge length for a simple cubic unit cell? Answer the same questions for the body-centered cubic unit cell and for the face-centered unit cell.
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In the LiCl structure shown in Figure 9.21, the chloride ions form a face-centered cubic unit cell 0.513 nm on an edge. The ionic radius of Cl- is 0.181 nm. (a) Along a cell edge, how much space is between the Cl- ions? (b) Would an Na+ ion (r=0.095nm) fit into this space? a K+ ion (r=0.133nm)?
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Crystalline polonium has a primitive cubic unit cell, lithium has a body-centered cubic unit cell, and calcium has a face-centered cubic unit cell. How many Po atoms belong to one unit cell? How many Li atoms belong to one unit cell? How many Ca atoms belong to one unit cell? Draw each unit cell. Indicate on your drawing what fraction of each atom lies within the unit cell.