F Draw the major product of this reaction. Ignore inorganic byproducts and the amine side product. 1. NaOH, heat H 2. Neutralizing work-up Drawing Q Pra Ator ar Draw c
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- Rank the following compounds in order of decreasing basicity, putting the most basic compound first. NH₂ A. || > | > ||| > IV B. | > | > ||| > IV C. | > ||| > | > IV D. IV> | > ||| > | NH₂ Br III NH₂ F3C IV NH₂Draw the major product of this reaction. Ignore inorganic byproducts and the amine side product. 1. NaOH, heat 2. Neutralizing work-up O Type here to searchDraw the major product of this reaction. Ignore inorganic byproducts and the amine side product. N' 1. H3O*, heat 2. Neutralizing work-up Select to Draw
- Ade ed arrows to show the Arte attack the proton of the acid (breaking the X-H bond * Identify the nucleophile and electrophile ectants but the charge will be on a different molecule.) Circle the conjugate base. charges of any lons OK a) HO, b) кон SH c) NO. ONa HO + Approximate pK, values of Important organic functional groups pk, Protonated Cacborylic alcohol R. -2 5. 10 Phenol 16 Alcohol 25 Alkyne 38 Amine acid 44 Alkene 50 1. H OH R-OH R -H Alkane R. R. он R H ROH Protonated N amine H. H Thiol R-SH4. Using curved arrows, draw a reaction mechanism and predict the products. Lewis Acid-Base Reaction of a) :: Bronsted Acid-Base Reaction b) P. + AICI3K Draw the initial organic product of the Bronsted acid- base reaction. Include all lone pairs and charges as appropriate. Ignore any counterions. H3O+ Drawing Question 5 Atoms,
- Determine which producevthe least basic primary amine 1. NaN3 2.H2/Pd Br А. H2/Pd,C 'NO2 Br 1. NaCN/HCI 2.H2/Pd,C С. D. A and C B.Lab 3: Reactions of Alcohols and Phenols Reactions of Alcohols and Phenols I. Circle the letter that best describes your unknown. elonod to ydibisA oT A a. Phenol b. Primary alcohol II. Which of the above possibilities best describes the antiseptic? c. Secondary alcohol d. Tertiary alcohol He roitulo OH III. Check below if a CH,-CH- group is present in a. your unknown. b. the antiseptic. onort- Questions fons 1. Which of the following reagents or tests would be most useful in quickly differentiating between CH, ab) t sldeT D. Oxidatiom with Ch O-CH,CH, – OH and -O- Table &(da a. Lucas reagent d. More than one answer is correct. lons b. Iodoform test c. Ferric chloride loniovo Explain your answer: 2. Which of the following reagents or tests would be useful in differentiating between propyl alcohol (CH3CH,CH2 – OH) and isopropyl alcohol (CH,CHCH,)? anwonlaU lo-noidsshsibnnd ОН b. Lucas reagent c. Aqueous bromine )& aidal Chromic acid d. More than one answer is correct. Explain your…5. a. Clearly identify the most acidic H atom in each of the structures shown below. Circle or draw it on the structure. ůl A B C b. Which of the compounds in part a can be completely deprotonated by NaOH? c. Which of the compounds in part a can be completely deprotonated by LDA? OH
- Be sure to answer all parts. Be sure to include the ion charges. Draw the products of the acid-base reaction. + H₂O B # # I draw structure # # # COE m # [AME MARE SHARE # draw structure ... Den POZZI higher molecular weight lower molecular weight product productDraw the major organic product of the Bronsted acid-base reaction. Include all lone pairs and charges. ----------NaNH2----------------->5. Circle the carbon atom that contains the most acidic C-H bond in this molecule e 6. The tertiary amine and aldehyde below will react to form a. An imine b. An enamine c. A nitrile d. None of the above 7. The secondary amine and aldehyde below will react to form HN, a. An imine b. An enamine c. A nitrile d. None of the above