Experiment 9C: Aldol Condensation (Data Sheet) Running the reaction • 0.44 g of dibenzyl ketone and O.43 g of benzil were dissolved in 3 mL of absolute ethanol in a 10 mL round-bottom flask After adding a spin bar and an air condenser, the mixture was heated to a gentle reflux 0.50 mL of ethanolic potassium hydroxide was added dropwise The color changed immediately from bright yellow to dark brown During the 10 min of reflux, a very dark precipitate formed Step 2 The syntheis of Tedraphenylayelipentadienone aldol conclensation Heaction. using ben zil and dibenzyl ketone . uun be done by double Reation Mechanism :- Ph. Ph Ph Ph Ph Ph Ph Ph Ph. Ph Ph Ph KOH Ph HO Ph Ph HO. Ph Ph P. Ph ph .Ph PhB Ph Ph HO -ao Ph Ph P Ph Ph Ph

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter23: Amines
Section23.6: Reactions With Acids
Problem 23.9P
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In the aldol reaction, why is it important to dissolve both ketones before the catalyst is added? 

Experiment 9C: Aldol Condensation (Data Sheet)
Running the reaction
0.44 g of dibenzyl ketone and 0.43 g of benzil were dissolved in 3 mL of absolute ethanol
in a 10 mL round-bottom flask
• After adding a spin bar and an air condenser, the mixture was heated to a gentle reflux
0.50 mL of ethanolic potassium hydroxide was added dropwise
The color changed immediately from bright yellow to dark brown
During the 10 min of reflux, a very dark precipitate formed
Step 2
The syntheis of Tebra phenylayelopentadienone
un be done by
double
aldol condlensation Heaction. using benzil and dibenzyl ketone .
Readion Mechanism :-
Ph.
Ph
Ph
Ph
Ph
Ph
Ph
Ph
Ph
Ph
-Ph
Ph
kOH
Ph
HO
Ph
Ph
OH
EtOH
Ph
Ph
Ph
Ph
Ph
Ph
PhB Ph
Ph
но
HO.
-auo
Ph
Ph
Ph
Ph
Ph
Transcribed Image Text:Experiment 9C: Aldol Condensation (Data Sheet) Running the reaction 0.44 g of dibenzyl ketone and 0.43 g of benzil were dissolved in 3 mL of absolute ethanol in a 10 mL round-bottom flask • After adding a spin bar and an air condenser, the mixture was heated to a gentle reflux 0.50 mL of ethanolic potassium hydroxide was added dropwise The color changed immediately from bright yellow to dark brown During the 10 min of reflux, a very dark precipitate formed Step 2 The syntheis of Tebra phenylayelopentadienone un be done by double aldol condlensation Heaction. using benzil and dibenzyl ketone . Readion Mechanism :- Ph. Ph Ph Ph Ph Ph Ph Ph Ph Ph -Ph Ph kOH Ph HO Ph Ph OH EtOH Ph Ph Ph Ph Ph Ph PhB Ph Ph но HO. -auo Ph Ph Ph Ph Ph
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