Example #3) 15mL of 2.0M HCl is mixed with 30mL of 0.75M KOH

Introduction to General, Organic and Biochemistry
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ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter6: Solutions And Colloids
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Example #3) 15mL of 2.0M HCI is mixed with 30mL of 0.75M KOH
HCI + KOH → H₂O + KCI
AHreaction =
Substance
H₂O
HC1
KC1
KOH
AHreaction=AHproducts-
AHreactants
AHreaction = (AHH20+ AHKCI) - (AHHCI + AHKOH)
AHreaction = (-286
+ -419
- 1kg1
Let's calculate the limiting reagent to determine how many mols of water will be formed:
Remember: Volume of reactant ÷ 1000 x Molarity of reactant x mole-to-mole ratio to water
Here's the first reactant: 15mL of 2.0M HCI
IS
1500
* 2.0
0.03 mol HCl
30
1000
Lof LOM KOH
Let's do this for the second reactant, 30mL of 0.75M KOH
0.75
0.0225 mol KOH
=
-)-(-164
-61
mol H₂O) x
AHf in kJ/mol
-286
-164
-419
-480
The limiting reagent is the compound that produced the fewest number of moles. Multiply that
number of moles buy the AH reaction that was calculated above
kJ/mol = -/-3725 kJ
-
+_ - 480
10.0225
Calcu
From here on out, you are on your own! Calculate the enthalpy of reaction, and then the
limiting reagent. Next multiply the enthalpy of reaction by the limiting reagent. Good luck!
Transcribed Image Text:Example #3) 15mL of 2.0M HCI is mixed with 30mL of 0.75M KOH HCI + KOH → H₂O + KCI AHreaction = Substance H₂O HC1 KC1 KOH AHreaction=AHproducts- AHreactants AHreaction = (AHH20+ AHKCI) - (AHHCI + AHKOH) AHreaction = (-286 + -419 - 1kg1 Let's calculate the limiting reagent to determine how many mols of water will be formed: Remember: Volume of reactant ÷ 1000 x Molarity of reactant x mole-to-mole ratio to water Here's the first reactant: 15mL of 2.0M HCI IS 1500 * 2.0 0.03 mol HCl 30 1000 Lof LOM KOH Let's do this for the second reactant, 30mL of 0.75M KOH 0.75 0.0225 mol KOH = -)-(-164 -61 mol H₂O) x AHf in kJ/mol -286 -164 -419 -480 The limiting reagent is the compound that produced the fewest number of moles. Multiply that number of moles buy the AH reaction that was calculated above kJ/mol = -/-3725 kJ - +_ - 480 10.0225 Calcu From here on out, you are on your own! Calculate the enthalpy of reaction, and then the limiting reagent. Next multiply the enthalpy of reaction by the limiting reagent. Good luck!
Example #4) 50mL of 1.5M HCI is mixed with 60mL of 1.0M KOH
HCI + KOH → H₂O + KCI
AHf in kJ/mol
-286
-164
-419
-480
Note: this is the same reaction as example #3, so the AH reaction should be the same
Substance
H₂O
HCI
KCI
KOH
AHreaction=AHproducts- AHreactants
AHreaction =
-biki
Let's calculate the limiting reagent to determine how many mols of water will be formed:
Here's the first reactant: 50mL of 1.5M HCI
50 * 1.5.
1000
1.5 = 0.075 mol Hel
Let's do this for the second reactant, 60mL of 1.0M KOH
60
1000
* 1 = 0.obmolkott
Calculate the amount of energy released:
Call 0.06 * -61 = -3.66 kg
Transcribed Image Text:Example #4) 50mL of 1.5M HCI is mixed with 60mL of 1.0M KOH HCI + KOH → H₂O + KCI AHf in kJ/mol -286 -164 -419 -480 Note: this is the same reaction as example #3, so the AH reaction should be the same Substance H₂O HCI KCI KOH AHreaction=AHproducts- AHreactants AHreaction = -biki Let's calculate the limiting reagent to determine how many mols of water will be formed: Here's the first reactant: 50mL of 1.5M HCI 50 * 1.5. 1000 1.5 = 0.075 mol Hel Let's do this for the second reactant, 60mL of 1.0M KOH 60 1000 * 1 = 0.obmolkott Calculate the amount of energy released: Call 0.06 * -61 = -3.66 kg
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