enolate addition (aka 1,2-addition). Write the 1. Addition of a nucleophile at the carbonyl carbon is called simple mechanism for simple addition of phenylmagnesium bromide to 3-buteneone. Concept 0-

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution
Section16.SE: Something Extra
Problem 30MP: The carbocation electrophile in a Friede1-Crafts reaction can be generated by an alternate means...
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Question one. 

I
dition
product
ble
dition
Як ибон-
on
دے
dition
product
gated
ddition
✓
✓
요.
요
liselt
O
NU
Solv-H
NU
NU
enolate
1. Addition of a nucleophile at the carbonyl carbon is called simple addition (aka 1,2-addition). Write the
mechanism for simple addition of phenylmagnesium bromide to 3-buteneone.
Concept -
OH
isto
NU
دے
个
Salv-H
Solv-H O-H
F
it
NU
0-
NU
Nu
2. Addition at the ß-carbon is conjugate addition (aka 1,4-addition). Write the mechanism for conjugate
addition of phenylmagnesium bromide to 3-buteneone.
ncept
mg
Bro
Phmg Br +
Br
t
16
H-OH
H
B
BYT
Mg Br-
OH
for
phy
४
OH
- Ph
VOD
ph
=
L
H₂O
(H-O
Transcribed Image Text:I dition product ble dition Як ибон- on دے dition product gated ddition ✓ ✓ 요. 요 liselt O NU Solv-H NU NU enolate 1. Addition of a nucleophile at the carbonyl carbon is called simple addition (aka 1,2-addition). Write the mechanism for simple addition of phenylmagnesium bromide to 3-buteneone. Concept - OH isto NU دے 个 Salv-H Solv-H O-H F it NU 0- NU Nu 2. Addition at the ß-carbon is conjugate addition (aka 1,4-addition). Write the mechanism for conjugate addition of phenylmagnesium bromide to 3-buteneone. ncept mg Bro Phmg Br + Br t 16 H-OH H B BYT Mg Br- OH for phy ४ OH - Ph VOD ph = L H₂O (H-O
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