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- Draw the structure(s) of the major organic product(s) of the following reaction. 1. lithium diisopropylamide/hexane 2.1 eq. CH₂l . Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, draw both stereoisomers. [Review Topics • Omit products derived from the acidic or basic reagent itself, e.g. HN(i-Pr), derived from N(/-Pr)₂. • If no reaction occurs, draw the organic starting material. [References] If substantial starting material is present at the end of the reaction, include it in the products. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with + signs from the drop-down menu. .Draw the structure(s) of the major organic product(s) of the following reaction. 1. lithium diisopropylamide / hexane 2. 1 eq. CH3I • You do not have to consider stereochemistry. • Omit products derived from the acidic or basic reagent itself, e.g. HN(1-Pr)2 derived from N(i-Pr)2 ". • If no reaction occurs, draw the organic starting material. • If substantial starting material is present at the end of the reaction, include it in the products. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate structures with + signs from the drop-down menu. ed opy aste ChemDoodleDraw the structure(s) of the major organic product(s) of the following reaction. 1. NaOCH3 / CH3OH H3C CH3 2. 1 eq. 2-bromo-2-methylpropane • You do not have to consider stereochemistry. • Omit products derived from the acidic or basic reagent itself, e.g. HN(i-Pr)2 derived from N(i-Pr),. • If no reaction occurs, draw the organic starting material. • If substantial starting material is present at the end of the reaction, include it in the products. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate structures with + signs from the drop-down menu. Draw the structure(s) of the major organic product(s) of the following reaction. Aqueous NaHCO3 0° C 1 eq. Cl2 • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, draw both stereoisomers. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional…
- Draw the structure(s) of the major organic product(s) of the following reaction. 1. lithium diisopropylamide / hexane 2.1 eq. Br •You do not have to consider stereochemistry. • Omit products derived from the acidic or basic reagent itself, e.g. HN(/-Pr)2 derived from N(i-Pr)2. •If no reaction occurs, draw the organic starting material. • If substantial starting material is present at the end of the reaction, include it in the products. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with + signs from the drop-down menu. • всGive the major organic product(s) of the following. Include stereochemistry when applicable. 1) Nal Br a) 2) NACN, acetone I) NAOC(CH,),, heat b) Br 2) BH; THF; 3) H,O,. NaOH(aq) 1) HCI 2) KOCICH,), heat 1) NAOH, heat Br 2) МСРВА 1) KOC(CH,), heat Br e) 2) H,0"Draw the structure(s) of the major organic product(s) of the following reaction. 2 eq. Cl₂ . Acetic acid You do not have to consider stereochemistry. • If there is more than one major product possible, draw all of them. • If no reaction occurs, draw the organic starting material. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu.
- Using your knowledge of general chemistry and organic chemistry, answer the following questions: Predict the relative acidities within each of the following groups, then identify the conjugate bases, and finally predict their relative leaving group abilities HClO3 and HClO2 PH3 and H2S [NH4]+ and [H3O]+ Explain why the trifluoromethane sulfonate (TfO-) ion is a better leaving group than the methanesulfonate (MsO-) ion.[Review Topics] [References] Draw the structure(s) of the major organic product(s) of the following reaction. 1. Ithium diisopropylamide /hexane Br 2.1 eq. • You do not have to consider stereochemistry. • Omit products derived from the acidic or basic reagent itself, e g. HN(-Pr)) derived from N(-Pr),. If no reaction occurs, draw the organic starting material. •If substantial starting material is present at the end of the reaction, include it in the products. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with - signs from the drop-down menu P.Draw the structure resulting from a reaction of: 1. diborane (B₂H6), followed by 2. alkaline hydrogen peroxide (NaOH / H₂O2) with the following alkene. . Use the wedge/hash bond tools to indicate stereochemistry where it exists. . If a group is achiral, do not use wedged or hashed bonds on it. • If the reaction produces a racemic mixture, just draw one stereoisomer.
- Compare isoquinoline and quinoline..Explain their basicity.Which of them will be more susceptible to nucleophilic attack and electrophilic attack ? Explain the reason?Predict the major products of the following reaction. Be sure to use wedge and dash bonds to show the stereochemistry of the products when it's important, for example to distinguish between two different major products...Heterocyclic compounds plays an important role in our daily life. They are mainly used in pharmaceutical and agrochemical products to name a few. 3. It is required to introduce a halogen group to a five membered ring, thiophene. Discuss the reaction mechanism involved in the reaction by selecting a suitable halogen group and analyze why a particular substituted product obtained after the reaction is predominant over the other possible product(s) with the help of reactions.