Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. In progress CH3 1. in benzene CH3-C-CI CH3 2. aqueous HCI • You do not have to consider stereochemistry. • If no reaction occurs, draw the organic starting material. Include the amine from which the enamine was derived. ⚫ Include counter-ions, e.g., Na+, I, in your submission, but draw them in their own separate sketcher. • • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. ? n [ ChemDoodle remove Submit Answer Retry Entire Group 7 more group attempts remaining Previous
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- Draw the structure(s) of the major organic product(s) of the following reaction. + 1. in benzene 2. aqueous HCI • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. Do not include the amine from which the enamine was derived. • • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. ? n ChemDoodle ⓇDraw the structure(s) of the major organic product(s) obtained after workup of the following reaction. о + сн CH₂-C-Cl CH3 1. in benzene 2. aqueous HCI You do not have to consider stereochemistry. • . If no reaction occurs, draw the organic starting material. • • • Include the amine from which the enamine was derived. Include counter-ions, e.g., Na+, I, in your submission, but draw them in their own separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Θ CH3 CH3 CH3 ? ChemDoodle" removeDraw the structure(s) of the major organic product(s) of the following reaction. 1. dioxane / 25° + CH3 2. aqueous acetic acid / reflux • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Do not include the amine from which the enamine was derived. • If no reaction occurs, draw the organic starting material. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. ? ChemDoodle
- Draw the structure(s) of the major organic product(s) of the following reaction after aqueous workup. O + + II... • You do not have to consider stereochemistry. • Include counter-ions, e.g., Na+, I, in your submission, but draw them in their own separate sketcher. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. H₂N Benzocaine topical anesthetic ? YDraw the structure(s) of the major organic product(s) of the following reaction. • • 1. in acetonitrile / reflux OCH3 2. aqueous HCI • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Do not include the amine from which the enamine was derived. • If no reaction occurs, draw the organic starting material. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu. Θ ? ChemDoodleⓇDraw the structure(s) of the major organic product(s) of the following reaction. 1. acetonitrile / reflux + Br 2. aqueous HCI • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. Do not include the amine from which the enamine was derived. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. ChemDoodle
- The following reaction, called the benzylic acid rearrangement, takes place by typical carbonyl group reactions. HO 1. NaOH, H₂O 2. H₂O* Ph OH Ph (Ph = phenyl) benzil benzylic acid Propose structures for the first two intermediates in this reaction. Ph You do not have to consider stereochemistry. • Do not include counter-ions, e.g., Na*, I, in your answer. • In cases where there is more than one answer, just give one. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate structures using the sign from the drop-down menu. ? Ph ·000 OO° [] ChemDoodleⓇ < 21Draw the structure(s) of the major organic product(s) of the following reaction after aqueous workup. NH₂ + CH3 CH3 . You do not have to consider stereochemistry. • Include counter-ions, e.g., Na+, I, in your submission, but draw them in their own separate sketcher. • If no reaction occurs, draw the organic starting material. • • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu. + H3C NH ? ChemDoodle √n [ An error has been detected in your answer. Check for typos, miscalculations etc. before submitting your answer.Draw the structure(s) of the major organic product(s) of the following reaction after aqueous workup. O + *** NH₂ + • You do not have to consider stereochemistry. • Include counter-ions, e.g., Na+, I, in your submission, but draw them in their own separate sketcher. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu. **** CH3 ? CH3 ChemDoodle O-Sn [1 Y
- Draw the product of the reaction between 2-pentanol and PBrą. ● ● ● ● You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. Do not include counter-ions, e.g., Na+, I-, in your answer. If no reaction occurs, draw the organic starting material. Sn [F ? ChemDoodleⓇB. A. propose a synthesis scheme for the following conversions. The indicated substrates should be your only/main source of carbon. Organic reagents may be used as necessary when part of a reaction covered (such as pyridine, PCC, etc). There are many ways to do these conversions. The HINTS are from 1 of the reactions I used in how I did the problem. X 40. HINT: Wittig HINT: Grignard + LOH ? ? OH PhOrganometallic reagents and alkoxides are strong bases as well as being good nucleophiles. Given the pKa values below, which reagent is the stronger base, nBuLi (CH3CH2CH2CH2LI) or the tert-butoxide anion ((CH3)3CO‒)? Explain your choice clearly in terms of structure andbonding. (Comparing the pKa values is not an explanation.) (CH3)3COH pka= 16.54CH3CH2CH2CH3 pka= 50