Draw the structures of organic compounds A and B. Indicate stereochemistry where applicable H2 H,O H3O* Lindlar's OH 1. NaNH2 catalyst H-C=C-H compound A compound B 2. CH;CH2CH,Br (1 equiv.)
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- Draw the organic product that is expected to form when the following compound is oxidized under biological conditions. (M) CH3 M oxidation 2req SH reduction M M) • You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • If no reaction occurs, draw the organic starting material. (M) C. P. aste opy M) = 2req s 2req M) M) ts ChomDondloDraw the structures of organic compounds A and B. Indicate stereochemistry where applicable H2 Lindlar's H2O H,O* OH 1. NaNH2 catalyst H-C=C-H compound A compound B 2. CH3CH2CH2Br (1 equiv.)4. What are the products obtained from the following elimination reaction? Indicate the major product. CH;CH2CCH3 H2O CI 5. a) Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction. CH;CH,CH,CH,CCH3 Br b) For the major elimination product obtained in 5a), which stereoisomer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.
- Draw the organic product of the following reaction. CH3 m-CICgH,CO;H • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, just draw one stereoisomer. • If more than one product is possible, only draw the major product. opy asteDraw tructu f he ajor rganic roduct f he ollowing reaction. CH2 1. Hg(OAc)2, H20 2. NaBH4 CH3 • In cases where there is more than one answer, just draw one. •You do not have to consider stereochemistry. [ドDraw the organic product(s) of the following reaction. CH3 H3C-C-CEC-H CH3 NaOC2Hs / CH5OH 1 eq. NANH2, NH3(1) CH;CH,CH,CH2-Br H-CEC-H H;C CH-Br H3C 1 eq. NaNH2, NH3() H3C-CEC-H
- Draw the structures of organic compounds A and B. Indicate stereochemistry where applicable H2 Lindlar's OH 1. NANH2 catalyst H,O* H-C=C-H compound A compound B 2. CH;CH,CH,Br (1 equiv.) Draw compound A. Draw compound B. Select Draw Rings More Erase Select Draw Rings More Erase H cH3) Complete the following reactions a) CH3CH2CHO CH2CH2COOH b) ? HCN CN KH HO NH2NHCgH5 ? c) H. CH3CH2M9CIO d) H3O* ÓHDraw the products of each reaction and indicate the stereochemistry at any stereogenic centers. CH,CH,OH CH;COCI pyridine a. OH C. CH5 COOH H* CH3 CH3 Br NaCN d. CH. HD "NH2 (2 equiv)
- A E OH OH H This is a(n) OH R B F PCC, CH₂Cl₂ H type reaction. The major product if R = CH₂CH3 is compound The major product if R = H is compound G Look at the given reaction and use the letter code corresponding to each compound in the blank to indicate the expected product(s), or fill in the blank with the appropriate vocabulary word or phrase. If a specific stereoisomer (e.g single enantiomer) is formed, select that isomer only. If a mixture of stereoisomers (e.g. racemic or diastereomers) is formed, select the single structure that shows the appropriate mixture (e.g. lines not dashes). If we convert the reagent to Na2CrO4, H₂SO4, H₂O: The major product if R = CH₂CH3 is compound The maior product if R = H is compound ??? OH D H H though compoundDraw the structure of the organic product or products formed in the reaction. H₂C HU IN. H HU of H₂ MgBr 1. H₂C A -CH₂ 2. H3O+ Select Draw / || III Rings C H MoreName the following compounds properly, including stereochemistry. CH3 H3C a) b) он Br e leom d Son lasal Br cle e en S) Draw the structures of the following compounds. a) acetonitrile Jud iyrdem snonet b) benzonitrile c) acetic acid d) formic acid outoge e) propyl propanoate y o trans Draw specific (no R's) examples of: the tet a) a hemiacetal b) a phosphorus ylide. c) an acid chloride d) a hydrate The reaction of acetone with NABH4 is a) a hydration b) a hydrolysis c) an oxidation d) a reduction pts) "Soap" may be defined as: a) a long chain carboxylic acid b) the sodium salt of a long chain acid c) the methyl ester of a long chain acid d) an anhydride of a long chain acid