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- 4. Draw the structure of product, substrate or condition in the following reactions (should clearly show the stereochemistry) a) HBr (2 equiv) b) 1) NaNH2 2) Ме 1) OsO4 2) NaHSO3 c) t-BUOK t-BUOH Hint: this is the only product formedDraw the appropriate curved arrows and products for each set of reactants undergoing a coordination step. Identify each reactant species as a nucleophile or electrophile. (a) NH₂ + AICI, →? (b) H₂O + BF₂? (c) ³0° H₂C OH - >?Q, - write a Mechanism that explains hint he stereochemisty (sed pmacal rearangemendy a) CotH6 fonn Hcl b) HeoH O wr,te he Mechanism fer OH CHBrg NAOH (Carbene)
- Indicate the directivity of the molecule below, and indicate if it is an 'activator' or a 'deactivator! Br O ortho-, para- directing activator O ortho-, para- directing deactivator meta- directing deactivator meta- directing activatorUse the References to access important values if needed for this question. Draw the structure of the product that is expected when the following compound is treated with concentrated H2SO4. он H2S04 ? heat CH3 You do not have to consider stereochemistry. • In cases where there is more than one answer, just draw one. ited opy Bste [F CH4 ChemDoodle Retry Entire Group 3 more group attempts remaining Submit Answer Previous Next Email Instructor Save and Exit Cengage Learning | Cengage Technical Support3) Complete the following: Stereochemistry and regiochemistry may be important. b) d) type type MeO Br type type type OH H Br E1 Reaction Borohydride Reduction H NaOAc DMF Асон HO PCC CH₂Cl2 H CO₂Et f) g) h) i) j) type type type type type OH OH Hydride Reduction MeHN Reductive Amination HO Br OH
- 2. What products would be obtained by treating A-D with NaOt-Bu in t-BuOH? Explain your reasoning, and if more than one product forms, indicate which product is major. Br A Br B C لي Br DWhich synthetic route(s) would complete the reaction shown? Br || ||| I and II O I and III ? HO OH + enantiomer Synthesis I: 1. NaCCCH3; 2. Na/NH3(I) ;3. OsO4; 4. NaHSO3, H₂O Synthesis II: 2. NaCCCH3; 2. H2, Lindlar's catalyst; 3. MCPBA; 4. aq. H₂SO4 Synthesis III: 1. NaCCCH3; 2. H₂, Pt; 3. MCPBA; 4. aq. H₂SO4a) b) O₂N of Draw the product of the first step as well as the second step including stereoisomers OH 1) BH3, THF 2) H3O+ 2) 1) KCN/HCN aja. ,NEt3
- Draw the major product of this reaction. Ignore inorganic byproducts. (CH3) SICI, Et N Drawing OHCyclohexanone do not produce isomeric oximes but cyclohexane does produces 2 stereoisomeric oximes. Explain whyDraw the organic product formed in the following reaction. H-N Job OEt OEt [1] NaOEt [2] CI [3] H₂O+, A NHAC HO "CH₂ edit structure ...