draw the entire synthesis of (8-Hydroxy-2-isopropyl-3,4-dihydroisoquinolin-1 (2H)-one) as mentioned in the picture ( with arrows, lone pairs, substitution and elimination)
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- If butanol underwent a self aldol addition reaction, what would be the major product 2-ethyl-2-hydroxyhexanol 2-ethyl-3-hydroxyhexanol (E)-2-ethyl-2-hexenal (Z)-2-ethyl-2-hexenal Both (Z) and (E)-2-ethyl-2-hexenalTrue or False The synthesis of dibenzalacetone is an example of Aldol condensation The synthesis of ethylacetoacetate from ethyl acetate is an example of Claisen Condensation Starting with a 1,6 - diester and treating it with NaOEt would be an example of Dieckmann Condensation If one starts with a 1,6 - diester then you will end up with a 5 membered ring A nucleophile that adds to the beta carbon of an alpha, beta unsaturated aldehyde or ketone would be considered softIn a William Ether Synthesis of Phenacetin experiment, the organic layer is washed twice with 5% aq. NaOH. The purpose of this step was to remove any unreacted acetaminophen from the organic layer by extracting it into the aqueous layer. 2. a) What reaction is occurring between acetaminophen and NaOH? Draw the reaction, mechanism, and product of this reaction step.
- 1. Complete the multi-step synthesis below by filling in the missing reagents in boxes (a) through (g). Write neatly! MgBr 1) 1) 2) 2) (a) (b) 1) (c) 2) OH (e) (f) (d) H3CO H3CO ОН (g)1. Draw mechanism (with electron pairs, flow of electrons, charges, and steps, where applicable) of base (B:) catalyzed condensation of your benzaldehyde and 2-methoxyethyl cyanoacetate4. Complete the retrosynthetic scheme below, involving a Friedel-Crafts acylation, by filling in all necessary reactants and reagents. mely ?
- H Aldol Reaction R. R مهمة RR OH R R Condensation Reaction R Dyle los H prip-pil Condensation Reaction RR OH R Aldol ReactionNeglecting stereoisomers, four different a,ß-unsaturated aldehydes are produced when the aldehydes shown below are mixed in the presence of NaOH/H2O, with heating. NaOH, H,O heat Draw structures for all four a,ß-uñsaturated aldehydes that would form in this crossed aldol condensation reaction. Include your answer in the single .pdf file that You uploadOthesis. teps neceossary to synthesize this compound by yl halide; after that you can add any organic or Dound. →1-hexanol )Consider the following compounds: B = HOCH2CH2CH2CH3 CH3 HC C = CH3CH2CH2OCH2CH2CH3 D = a) Which one(s) could be reduced with NaBH4? b) Which one(s) would give a positive Tollens silver mirror test? c) Which one(s) could be oxidized with CrO3? d) Which one(s) would react with 1 or 2 equivalents CH3M9B to make a npound butyl ethyl ether larger alcohol?
- Draw the alkyl bromide(s) you would use in a malonic ester synthesis of ethyl cyclopentanecarboxylate. You do not have to consider stereochemistry. If no reaction occurs, draw ethyl cyclopentanecarboxylate. If more than one alkyl bromide is needed, draw them all. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with + signs from the drop-down menu.3) Provide example reactions for Aldol and Claisen condensations. [self-study not grade: For each of your example reactions, use the product as a starting material for another reaction.]Draw resonance structures of anisole or the intermediate in the above reaction to demonstrate why the methoxy group is an o,p-director