Draw a reaction with reactant(s) and expected product(s) for each of the 6 alkyl halides in the SN1 reaction. If no product formed for any of the reactions indicates no reaction . In SN1 1% silver nitrate in ethanol was used to react with 6 alkyl halids 1-chlorobutane, 2-chlorobutane, Allyl chloride, 2-chloro-2-methylpropane, 1-chloro-2-methylpropane, 2-bromobutane

Draw a reaction with reactant(s) and expected product(s) for each of the 6 alkyl halides in the SN1 reaction. If no product formed for any of the reactions indicates no reaction . In SN1 1% silver nitrate in ethanol was used to react with 6 alkyl halids 1-chlorobutane, 2-chlorobutane, Allyl chloride, 2-chloro-2-methylpropane, 1-chloro-2-methylpropane, 2-bromobutane

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter16: Aldehydes And Ketones

Section: Chapter Questions

Problem 16.26P: Wittig reactions with the following -chloroethers can be used for the synthesis of aldehydes and...

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Wittig reactions with the following -chloroethers can be used for the synthesis of aldehydes and ketones. (a) Draw the structure of the triphenylphosphonium salt and Wittig reagent formed from each chloroether. (b) Draw the structural formula of the product formed by treating each Wittig reagent with cyclopentanone. Note that the functional group is an enol ether or, alternatively, a vinyl ether. (c) Draw the structural formula of the product formed on acid-catalyzed hydrolysis of each enol ether from part (b).
Secondary halides can react via SN1 or SN2 reactions depending on reaction conditions. Draw the starting material and products that would be formed from the reaction of (R)-2-bromobutane with methanol via an SN1 and SN2 reaction.
Arrange the following alky halides in order of decreasing reactivity in an SN1 reaction: 2-bromopentane, 2-chloropentane, 1-chloropentane, 3-bromo-3-methylpentane
Give the products of the following substitution reactions. For every reaction, show electron pairs on both nucleophile and leaving group.
Choose the best reagents from the list provided below for carrying out the following conversion. Match the reagent with the step number. HCl (aq), Zn(Hg) Br2, FeBr3 Na/NH3, -33 degrees C NBS, light KMnO4, H3O+ Mg metal, ether KOH, EtOH, heat
1-bromo-1-methylcyclopentane is being reacted with sodium ethoxide in diethyl ether Ethoxide will remove a proton from one of the carbons alpha to the carbon bonded to bromine. The electron pair from the carbon-hydrogen bond will move toward the 1 carbon to form a new pi bond. This will push off the bromine, which will leave with its electron pair to form a bromide leaving group. This will form the product 1-methylcyclopentene and sodium bromide as byproduct. So, is this reaction following an E1 or E2 mechanism? Write out the rate law for this reaction. Draw a reaction coordinate diagram for this reaction.
name the major product for the reaction of 4-methyl-1-pentyne with the following reagents 1 mol HBr 2 mol HBr 1 mol Br2/CH2Cl2
The following reaction involves two sequential Heck reactions. Draw structural formu- las for each organopalladium intermediate formed in the sequence and show how the final product is formed. Note from the molecular formula given under each structural formula that this conversion corresponds to a loss of H and I from the starting material. Acetonitrile, CH,CN, is the solvent. 1% mol Pd(OAc), 4% mol Ph,P CH,CN C4H171 C4H16
Identify the substitution products that form when 2-bromo-2-methylpropane is dissolved in a mixture of 80% ethanol and 20% water. a. Explain why the same products are obtained when 2-chloro-2-methylpropane is dissolved in a mixture of 80% ethanol and 20% water.
Solvolysis of 2-jodo-2-methylpentane in propanoic acid containing potassium propanoate gave three products. Select the three products generated from this reaction. 4-methyl-2-pentene (or 4-methylpent-2-ene) 3-methyl-2-pentanol (or 3-methylpentan-2-ol) 1,1-dimethylbutyl propanoate (or 2-methylpentan-2-yl propionate) 2-methyl-2-pentene (or 2-methylpent-2-ene) 2-methyl-1-pentene (or 2-methylpent-1-ene) 2-methyl-2-pentanol (or 2-methylpentan-2-ol) X 86)
In the E2-elimination reaction of propyl bromide with sodium ethoxide, a graduate student performed two separate kH/kD experiments. In the first experiment, the student labeled the internal CH2 group with deuterium and compared the rate of this deuterated reactant to that of the protio propyl bromide. In the second experiment, the student labeled the CH2 group attached to the bromide with deuterium and compared the rate of the protio propyl bromide. Predict and rationalize the magnitude for the expected kH/kD for each of these experiments? Classify the isotope measured in each of these experiments as primary/secondary and normal/inverse
rank them according to their reactivity in an Sn2 reaction. isopropyl e-methylbenzenesulfonate, vinyl chloride, tert butyl chloride