Dinitrogen tetroxide decomposes reversibly in the gas phase to form nitrogen dioxide according to N2O4(g) 2NO2(g) The Gibbs energy of formation (A,Gº) at 298 K for N₂O4(g) is +97.89 kJ mol-¹ and for NO2(g) is +51.31 kJ mol-1. Calculate the standard reaction Gibbs energy (A,Gº) (298 K) for the reaction.

Dinitrogen tetroxide decomposes reversibly in the gas phase to form nitrogen dioxide according to N2O4(g) 2NO2(g) The Gibbs energy of formation (A,Gº) at 298 K for N₂O4(g) is +97.89 kJ mol-¹ and for NO2(g) is +51.31 kJ mol-1. Calculate the standard reaction Gibbs energy (A,Gº) (298 K) for the reaction.

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter8: Thermochemistry

Section: Chapter Questions

Problem 90QAP: Consider a metal ion A2+ and its nitrate salt, In an experiment, 35.00 mL of a 0.217 M solution of...

See similar textbooks

Similar questions

Consider the reaction NH4+(aq) H+(aq)+NH3(aq) Use G f for NH3(aq) at 25C=26.7 kJ/mol and the appropriate tables to calculate (a) G at 25C (b) Ka at 25C
Actually, the carbon in CO2(g) is thermodynamically unstable with respect to the carbon in calcium carbonate(limestone). Verify this by determining the standardGibbs free energy change for the reaction of lime,CaO(s), with CO2(g) to make CaCO3(s).
Describe a nonchemical system that is not in equilibrium, and explain why equilibrium has not been achieved.
5.49. Consider the following equilibrium: What is the effect on the equilibrium of each of the following changes? (You may need to calculate some standard enthalpy or Gibbs energy changes to answer these.) (a) The pressure is increased by decreasing the volume. (b) The temperature is decreased. (c) The pressure is increased by the addition of nitrogen gas, .
For the system 2SO3(g)2SO2(g)+O2(g) K=1.32 at 627. What is the equilibrium constant at 555C?
Determine the equilibrium constant for the reaction Sn+Pb2+Sn2++Pb
Suppose you have an endothermic reaction with H = + 15 kJ and a S of 150 J/K. Calculate G and Keq at 10, 100, and 1000 K.
Another step in the metabolism of glucose, which occurs after the formation of glucose6-phosphate, is the conversion of fructose6-phosphate to fructose1,6-bisphosphate(bis meanstwo): Fructose6-phosphate(aq) + H2PO4(aq) fructose l,6-bisphosphate(aq) + H2O() + H+(aq) (a) This reaction has a Gibbs free energy change of +16.7 kJ/mol of fructose6-phosphate. Is it endergonic or exergonic? (b) Write the equation for the formation of 1 mol ADP fromATR for which rG = 30.5 kJ/mol. (c) Couple these two reactions to get an exergonic process;write its overall chemical equation, and calculate theGibbs free energy change.
Given the following data: PtCl42(aq)+2ePt(s)+4Cl(aq)Ered=0.73VPt2+(aq)+2ePt(s)Ered=1.20V Find Kffor PtCl42- at 25°C.
Consider a metal ion A2+ and its nitrate salt, In an experiment, 35.00 mL of a 0.217 M solution of A(NO3)2 is made to react with 25.00 mL of 0.195 M NaOH. A precipitate, A(OH)2, forms. Along with the precipitation, the temperature increases from 24.8C to 28.2C. What is H for the precipitation of A(OH)2? The following assumptions can be made. â€¢ The density of the solution is 1.00 g/mL. â€¢ Volumes are additive. â€¢ The specific heat of the solution is 4.18 J/g C.
5.11. Determine the numerical value of Q for the reaction conditions indicated.
Calculate the standard Gibbs free-energy change when SO3 forms from SO2 and O2 at 298 K. Why is sulfur trioxide an important substance to study? (Hint: What happens when it combines with water?)