Determine the point group of the following planar Pt(II) complexes: Pt(NH3)42: PtCl3(NH3); PtCI(NH3)3 O C2hi C2vi D2d OD2h: D2d: C2zv O Dahi D2d: C2v O Cavi Cavi Cav OD4h: C2vi C2v
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- An octahedral complex, MA,B,C2 (A, B, C are all monodentate ligands), has a total of 6 stereoisomers. Considering the point groups for each of these isomers, it can be concluded that none of these isomers has the following point group. C2v C1 D2h Which cation is mostly likely to form a complex with SCN' b CsWhat point group is produced if an octahedral (Oh) complex is distorted by stretching two trans M-L bonds and compressing another two trans bonds? D4h D2d D2h C4vConsider IF3O2 (with I as the central atom). How many isomers are possible (draw them)?Which is likely to be the most stable isomer AND why? Assign the point group designation to each isomer.
- What are the point groups of a tetragonally compressed tetrahedral and square planar geometry of this complex?Draw the shape of the [XeF5]- ion and answer the questions below: (ii) What is the point group of the [XeF5]- ion? What is the order of the point group of the [XeF5]- ion?Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the following isomers answer the following questions: CN CN .... CI CN NC CI Isomer A Isomer B What is the point group of each isomer? C2v D2h Isomer A: Isomer B: а. Determine the reducible and irreducible representations corresponding to the CN stretching of Isomer A. b. Determine the reducible and irreducible representations corresponding to the CN stretching of Isomer B. With the information learned, can these 2 isomers be distinguished with IR spectroscopy? с.
- 2. Consider IF3O2 (with I as the central atom). How many isomers are possible (draw them)? Which is likely to be the most stable isomer AND why? Assign the point group designation to each isomer.Q8 draw the appropriate symmetry-adapted linear combinations and the molecular orbital diagram for o bonding in a square-planar complex. The point group is Dah. Take note of the small overlap of the ligand with the d,' orbital. What is the effect of t bonding?What is the point group and polarity of perbromobenzene?
- Help me pleaseFor the ground state terms of the d4 and d7 electronic configurations, determine the splitting of the ground state terms in the square planar (D4h) ligand field. Do the same for the f3 and f6 ground state terms in a C2v field. Just the ground states.Determine the point group of the following. Consider all square planar PtCl4²- Pt(CO)Cl3 cis-Pt(CO)2Cl2 trans-Pt(CO)2Cl2