Consider the structure of raffinose, a trisaccharide found in sugar beets and a number of higher plants. Но CH,OH HO OH OCH, Но Но OH HOCH, но CH,OH OH raffinose (a) Classify raffinose as a reducing or nonreducing sugar, and tell how you know. (b) Identify the glycoside linkages in raffinose, and clas- sify each as either a or B. (c) Name the monosaccharides formed when raffinose is hydrolyzed in aqueous acid. (d) What products are formed when raffinose is treated with dimethyl sulfate in NaOH, and then with aqueous acid and heat?

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter25: Carbohydrates
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Problem 25.39P
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Consider the structure of raffinose, a trisaccharide found
in sugar beets and a number of higher plants.
HO
CH,OH
Но-
OH
OCH,
Но
Но
OH
НОСН
Но
CH,OH
ÓH
raffinose
(a) Classify raffinose as a reducing or nonreducing sugar,
and tell how you know.
(b) Identify the glycoside linkages in raffinose, and clas-
sify each as either a or B.
(c) Name the monosaccharides formed when raffinose is
hydrolyzed in
aqueous
acid.
(d) What products are formed when raffinose is treated
with dimethyl sulfate in NaOH, and then with aqueous
acid and heat?
Transcribed Image Text:Consider the structure of raffinose, a trisaccharide found in sugar beets and a number of higher plants. HO CH,OH Но- OH OCH, Но Но OH НОСН Но CH,OH ÓH raffinose (a) Classify raffinose as a reducing or nonreducing sugar, and tell how you know. (b) Identify the glycoside linkages in raffinose, and clas- sify each as either a or B. (c) Name the monosaccharides formed when raffinose is hydrolyzed in aqueous acid. (d) What products are formed when raffinose is treated with dimethyl sulfate in NaOH, and then with aqueous acid and heat?
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