Consider the plot below. State it represents what mechanism and why the slope at lower [A] is different than the slope at higher [A high [A]: log kobs = log 2.0 k' 1.5 1.0 0.5 low [A]: log kobs = log k. + log[A] 0.00 -4.5 -2.5 -0.5 log ([A]/ mol dm-3)

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter20: Kinetics
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Problem 20.75E: A proposed mechanism for the gas-phase chlorination of methane is...
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Consider the plot below. State it represents what mechanism and why the slope at lower [A] is different than the slope at higher [A
high [A]:
kk,
log kobs = log
k',
2.0
1.5
1.0
0.5
low [A]:
log kobs
= log k, + log[A]
0.00
-4.5
-2.5
-0.5
log ([A]/ mol•dm-3)
log (kobs/s-1)
Transcribed Image Text:Consider the plot below. State it represents what mechanism and why the slope at lower [A] is different than the slope at higher [A high [A]: kk, log kobs = log k', 2.0 1.5 1.0 0.5 low [A]: log kobs = log k, + log[A] 0.00 -4.5 -2.5 -0.5 log ([A]/ mol•dm-3) log (kobs/s-1)
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