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Consider the following elementary reaction mechanism where both the forward and reverse reactions are important: kf1 CO+O₂ CO₂ +0 kr1 O+H₂O OH+OH kf2 kr2 Kf3 CO+OHCO₂ + H k,3 2 kƒ4 H+0₂ ⇒OH+O kr 4 1. Write all chemical rate differential equations that are needed to determine the chemical evolution of the system. Write all initial conditions that are needed to determine the chemical evolution of the system. 2. 3. Is this system of rate differential equations sufficient to solve for the evolution of compositions of each chemical species? Explain, including a discussion of what else might be needed.

Consider the following elementary reaction mechanism where both the forward and reverse reactions are important: kf1 CO+O₂ CO₂ +0 kr1 O+H₂O OH+OH kf2 kr2 Kf3 CO+OHCO₂ + H k,3 2 kƒ4 H+0₂ ⇒OH+O kr 4 1. Write all chemical rate differential equations that are needed to determine the chemical evolution of the system. Write all initial conditions that are needed to determine the chemical evolution of the system. 2. 3. Is this system of rate differential equations sufficient to solve for the evolution of compositions of each chemical species? Explain, including a discussion of what else might be needed.

Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.65P
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Consider the following elementary reaction mechanism where both the forward and reverse reactions are important: kf1 CO+O₂ CO₂ +0 2 kr1 O+H₂O OH+OH kƒ2 kr2 kƒ3 CO+OH=CO,+H k₁.3 kf4 H+0,⇒OH+O kr 4 1. Write all chemical rate differential equations that are needed to determine the chemical evolution of the system. 2. Write all initial conditions that are needed to determine the chemical evolution of the system. 3. Is this system of rate differential equations sufficient to solve for the evolution of compositions of each chemical species? Explain, including a discussion of what else might be needed.
Transcribed Image Text:Consider the following elementary reaction mechanism where both the forward and reverse reactions are important: kf1 CO+O₂ CO₂ +0 2 kr1 O+H₂O OH+OH kƒ2 kr2 kƒ3 CO+OH=CO,+H k₁.3 kf4 H+0,⇒OH+O kr 4 1. Write all chemical rate differential equations that are needed to determine the chemical evolution of the system. 2. Write all initial conditions that are needed to determine the chemical evolution of the system. 3. Is this system of rate differential equations sufficient to solve for the evolution of compositions of each chemical species? Explain, including a discussion of what else might be needed.
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