Consider a battery made with the overall reaction:

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter8: Electrochemistry And Ionic Solutions
Section: Chapter Questions
Problem 8.37E
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Consider a battery made with the overall reaction: 

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Comparing the reduction potentials it is clear that silver will be the cathode and copper will be the anode.

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