CONCEPTUAL CHECKPOINT21.10 Predict the major product for each of the following reaction sequences:OH1) Br2, PBr32) H₂O?a.gouOH1) Br₂, PBr32) H₂O?b.21.11 Identify reagents that can be used to accomplish each of the following transformations (you will also need touse reactions from previous chapters).a.b.CNBrOHCOOHBrBrСОНOHBr

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Answered: CONCEPTUAL CHECKPOINT 21.10 Predict the…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Provide the major organic product(s) that complete the following reaction equations. Please include stereochemistry (R/S, E/Z) where applicable 1) H2 Lindlars cat. 2) Cl2, DCM Me H. K 1) PBr3 pyridine 2) NaCN OH OH H2SO4 (cat.) Ме 1) H2SO4 H20 2) NaOCI CH;CO2H, 0 °C 7
12.13 a) Predict the products of the following reactions and draw mechanisms showing their formation. Br₂ NaHCO. MeOH 1) II) IV) HO OH OH Тон OH OH PCC CH₂Cl₂ H₂CrO₂ H₂O, H₂SO₂ H₂CrO H₂O, H.SO
Which conditions will produce the target product in the highest yield? O A) 1. BH3; 2. H₂O₂, NaOH, H₂O B) 1. OsO; 2. S(CH3)2 C) 1. Hg(OAc)₂, H₂O; 2. NaBH4 D) H₂SO4, H₂O A ? B OH racemic mixture
For the following reactions, provide all products, identify the mechanism and indicate the major product (if appliable). 1) O3 2) DMS а. Br2, H20 b. Cl2, H2O с. HBr d. Xo
3:26 PM Tue Apr 26 l : 42% O +: 0 b. Provide mechanisms and/or products for the following transformations. Pd°Ln, Cul, PhBr 1. HBpin, THF ? ? EtgN, THF H. 2. Pd°Ln, PhBr, KGPO4, H2O/THF 4
Which reaction sequence will most successfully generate the product shown below (1) HNO 3/H2SO4 (A) (2) KMNO4, H* , H20 (3) SnCl2/HCI (1) KMNO4, H* , H2O (B) (2) HNO-/H,SO, (3) SnCh/HC [?] HOOC. NH2 (1) HNO3/H2SO4 (C) (2) SnCl/HCI (3) KMNO4, H*, H2O (1) SnCh/HCI (D) (2) KMnO H. HO (3) HNO/H,SO4 4+ Sequence B Sequence D Sequence C Sequence A
PART C: Provide the major organic product(s) that complete the following reaction equations. Please include stereochemistry (R/S, E/Z) where applicable 7) 1) SOCI, pyridine 2) NaSPh OH 8) 1) H2SO4 H20 2) NaOCI CH;CO,H, 0 °C 9) H2SO4 (cat.) он Me Me 10) Me Et 11) (r Me Me Cl2 CH3OH 0o 을
2. Give the mechanism and products for the reaction sequence below: H-Br (1 eq.). -H- 1. Hg(OAc)2 / H2O 2. NaBH4
Reagent 3 list; commas separate the choices benzylamine,cyclohexlbromide, cyclohexylamine NaBH3CN catalytic H+, h30, NaOH Reagent 4 list; CH3(Ch2)2MgBr, cyclohexylamine NaBH3CN catalytic H+, Na2 Cr2 O7 H2O H2SO4,cyclohexabromide reagent 5 list; cyclohexylamine NaBH3CN catalytic H+,CH3(Ch2)2MgBr, cyclohexabromide, benzylamine
1) Predict the final product of the following reaction sequences. Draw the major product in each case, unless otherwise noted. Include structures and mole ratios of all carbon-containing products: 2 eq. HIO4 Он а. 1) Fe/HCI, then H20 2)HONO, 0 - 5°C 3) H2O, Cu20, Cu(NO3)2 NO2 4) NaH, Br b. 5) Heat (200°C) 1) HNO3/H2SO4 2) SOCI2 3) NaN3, the heat and H20 OH 4) NaNO2, HCI, H2O 5) NaOH, H2O, and LOH
2. Predict the products of the following reactions, paying careful attention to which FG would react in each situation. Br Br OH OH 1) TsCl, pyridine 2) 1 equiv NaCN MeOH mod. heat Br Br OH OH 2 equiv NaOEt 1) PBr3 2) Nal in DMF
Show how products A, B and C can be derived from each of the starting material. More than one step is required. (i). (ii). (iii). OH OH Step 1 Step 2 Step 1 Step 2 Step 1 Br -Br Compound A Compound B Step 2 CI OH Compound C

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