compound A using the data below. Assign each signal and give the multiplicity and relative integrations. Explain your reasoning. H Cl3P You may assume that: ■ 31P, I = ½2, is 100% abundant; RhH ☐ 103 Rh, I = ½ is 100% abundant; pCl3 • ¹H, I = 2 100% abundant. - Only 1- and 2-bond couplings are observed; -1-bond couplings are larger than 2- bond couplings,

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter19: Nuclear Magnetic Resonance Spectroscopy
Section: Chapter Questions
Problem 19.20QAP
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(c) (i) Predict and sketch the ¹H, 31P and 103Rh NMR spectra of
☐
compound A using the data below. Assign each signal and give the
multiplicity and relative integrations. Explain your reasoning.
▪
H...
Cl3P
RhH
You may assume that:
31P, I = ½2, is 100% abundant;
103Rh, I = 1/2 is 100% abundant;
¹H, I = ½ 100% abundant.
▪ Only 1- and 2-bond couplings are observed;
☐ 1-bond couplings are larger than 2- bond couplings,
PC13
Transcribed Image Text:(c) (i) Predict and sketch the ¹H, 31P and 103Rh NMR spectra of ☐ compound A using the data below. Assign each signal and give the multiplicity and relative integrations. Explain your reasoning. ▪ H... Cl3P RhH You may assume that: 31P, I = ½2, is 100% abundant; 103Rh, I = 1/2 is 100% abundant; ¹H, I = ½ 100% abundant. ▪ Only 1- and 2-bond couplings are observed; ☐ 1-bond couplings are larger than 2- bond couplings, PC13
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