Compound A is formed from the reaction of benzene with CH;CI in the presence of AICI3. Oxidation of A with reagent B produce C; chlorination of A in the presence of light gives D. Suggest structural formula of A, C and D and give reagent B. Propose all the reactions involve in the initiation and termination steps for the chlorination of A to D. Name the reaction that convert benzene to A and write the mechanism involved.

Compound A is formed from the reaction of benzene with CH;CI in the presence of AICI3. Oxidation of A with reagent B produce C; chlorination of A in the presence of light gives D. Suggest structural formula of A, C and D and give reagent B. Propose all the reactions involve in the initiation and termination steps for the chlorination of A to D. Name the reaction that convert benzene to A and write the mechanism involved.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter9: Alkynes: An Introduction To Organic Synthesis

Section9.SE: Something Extra

Problem 50AP

See similar textbooks

Similar questions

Hydrocarbon A, C9H12 absorbs 3 equiv. of hydrogen to give B, C9H18 when hydrogenated over a Pd/C catalyst. Treatment of A with aqueous H2SO4 and Hg(II) gives two isomeric ketones, C & D. Oxidation of A with KMnO4 gives acetic acid and the tricarboxylic acid E shown below. Propose a structure for A.
An unknown alcohol C6H14O gave a rapid Lucas Test. It could not be oxidized easily, but upon treatment with acid, the alcohol was converted to olefin, C6H12. Ozonolysis of the alkene gave two differentc arbonyls as products, both of which had the molecular formula C3H6O. What was the structure of thea lcohol, the olefin and the carbonyl compounds?
Compound AA, C6H14O, reacts very fast and immediately form a cloudy solutionwith Lucas reagent. Compound BB, an alkene is formed when compound AAreacted with concentrated sulfuric acid, H2SO4.Ozonolysis process of compoundBB will produce only propanone. Reduction of propanone with Nickel, Ni givescompound CC. Esterification of compound CC with propanoic acid producescompound DD. Draw the structural formula of compounds AA, BB, CC, and DD
Carototoxin is a natural pesticide produced by carrots, with formula C₁H2O. It undergoes hydrogenation with Pd to: give product A, C,H,O, and with Lindlar's catalyst to give product B, C,H2O. Ozonolysis followed by zinc leads to a mixture of methanal, octanal, 1,2-ethanedioic acid, 3-oxopropanoic acid, and 2-hydroxy-3-oxopropanoic acid. Draw possible structures for carototoxin, A, and B. Product B structure H2, Lindlar's Structure of carototoxin H2, Pd/C Product A structure
What is the structural requirement for a substance to react with ammoniacal AgNO3? Why would acetylene react with Tollen's reagent but not cyclohexane or cyclohexene?
Hydrocarbon A has the formula C9H12 and absorbs 3 equivalents of H2 to yield B, C9H18, when hydrogenated over a Pd/C catalyst. On treatment of A with aqueous H2SO4 in the presence of mercury(II), two isomeric ketones, C and D, are produced . Oxidation of A with KMnO4 gives a mixture of acetic acid (CH3COOH) and the tricarboxylic acid E. Propose structures for compounds A-D, and write the reactions.
An alkene with molecular formula C8H16 was obtained from ozonolysisreaction and give acetone and 2,2-dimethylpropanal as the product. Writethe chemical equation from the reaction
12:53 ul 4G O 2. Show a reaction scheme with all the reactants and reagents of the nitration reaction of bromobenzene and show the major products(s), with valid reasons motivate why the positioning of the two constituents' favour ortho, para and/or meta positioning Add a caption... > Status (Custom) +
The academic version of the process invention program (PIP) contains several examples, as follows: HDAl-hydrodealkylation of toluene to produce benzene CYHEXl-cyclohexane production by hydrogenation of benzene STYRl-styrene production from ethylbenzene XYLl-production of m-xylene from toluene ANHYDl-reaction of acetone and acetic acid to form acetic anhydride BUTALl-alkylation reaction of butene-1 and isobutane to produce iso-octane Select the “new plant design” mode and the “look at existing flow sheet” option, and follow the synthesis steps for one of these processes. ‘Obtain the current flow sheet as output at each level of the synthesis procedure. Also list the heuristics used at each step.
Compound A (C7H11Br) is treated with magnesium in ether to give B (C7H11MgBr), which reacts violently with D2O togive 1-methylcyclohexene with a deuterium atom on the methyl group (C). Reaction of B with acetone (CH3COCH3)followed by hydrolysis gives D (C10H18O). Heating D with concentrated H2SO4 gives E (C10H16), which decolorizestwo equivalents of Br2 to give F (C10H16Br4). E undergoes hydrogenation with excess H2 and a Pt catalyst to giveisobutylcyclohexane. Determine the structures of compounds A through F, and show your reasoning throughout
Treatment of propylbenzene with NBS + hv affords a single constitutional isomer. Suggest a structure for the product and a reason for its formation.
Devise a route to convert propene to propanone. Specify, in order, the reagents you would use. The reaction may require more than one step. If there is more than one feasible route, show only one. a NBS b H₂, Pd c H₂O, H₂SO4 d PCC e Br₂ in H₂O f K₂Cr₂O7, H₂SO4, H₂O, heat g Cl₂, heat or light h Cl2 i HCI j NaOH k OsO4/H₂O2 1. BH3 2. H₂O2, NaOH m SOCI2₂, pyridine I n Specify reagents using letters from the table, first reagent on the left. Example: ab The reagents are (in order of use): HBr o Br2,