CO₂E1 i CH3CHCO₂E 1. Na* "Ot 2. PhBr 3. H30, heat The intended reaction is the because the alkyl halide used is CH3 CHCO₂H which involves alkylation of the enolate ion. However, the reaction will not occu since the is prevented.
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- What is the intermediate before the final product of the following reactions? ii NaOH H* heat O a. Na Ob. OH OH Od. Na* он e. Of.The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?Explain why ethene does not react with HX ( X=Cl , Br or I) under normal conditions.
- How is this reaction classified? R DG TXI Reaction progress Free energy з O a Endergonic O b. Electrophilic Addition Oc. Nucleophilic Addition O d. Exergonic PHO 2. Complete the following reactions by filling in any missing reactants, reagents or products. a) Zn(Hg) conc. HCI b) OH olamee hoosla bas im 0.011o om me Im 0.01 1o smulov c) awiboa lo omnl C sid gnien) to omi 010 CHO. РСС CH,Cl,4. Draw structures for products of the following reactions. PaCl, (Bu water tBu PdCI, methanol OH CHCI, NaOH, water Me,N LDA, THE, 0°C BulI (2 moles) Bri THF, -78°C Buli THE, °C Br Pd(OAch THE, 0C MeO
- Select the major organic product of this reaction. H3C H3C A D E B ( A OTS OTS НО. H3C D NaOH, H₂O B ▪OTS ***OH H3C product HO.. E OH -OTSa) Propose the products of the following reactions of Lactone P. T 1. LIAIH,, ether 2. Н.О 1. DIBAL S NaOH H;O* 2. H;O* Lactone (P) 2 CH,MgBrQUESTION 33 Which of the following rate laws accurately describes the rate determining step in an Et elimination of alcohols? OA Rate - Mearbocationproton OH. Rate = kfoxonium lon)[alcohol O cRate kfcarbocation] OD Rate = loxonium lon] OE Rate kcarbocation][water) QUESTION 34 Aqtuieous KMnO4 which is purple, indicatos the presence of alkenos by reacting with them to forn coioriess precipitate and OA. none of the answers OR 12 diols, molybdenum dioxide, orange Or vicinal diols, manganese dioxide. brown O D. glycols, magnesium dioxide, brown OE alkyl chlorides, potasslum hydroxide, yellow O F. geminal diols, manganese dioxide, brown QUESTION 35 five carbon (S)-(+) Carvone was isolated from caraway seeds and belongs to a group of natural compounds called O steralds, one pentane O alkaloids, three, tert-butyl O terpenoids, two, isoprene which contain subunit(s) pentanoids, one, pentane O None of the above
- 1c. What is the nucleophile in the following reaction? .Br CH;CO0 Na LO OCCH3 NaBr ld. What is the electrophile in the following reaction? Br CH;COO Na L0OCCH3 NaBr +What is the major organic product of the following reaction? OI || ||| OIV OV 1. LIAH, 2. H₂0 H₂N 101Benzoic acid reacts with AlCl3 and 2-hexanone to produce what? Draw the product, including arrows showing what happened.