Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter24: Biochemistry
Section: Chapter Questions
Problem 4PS
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Concept explainers
Organomagnesium compounds
The interaction of alkyl halide with Mg metal in a suitable ether solvent is the common method for the synthesis of the Grignard reagent.
Hydrolysis Grignard Reactions and Reduction
Organomagnesium halides are Grignard reagents. Francois Auguste Victor Grignard, a French chemist who received the Nobel Prize in Chemistry in 1912, created these highly useful reagents.
Question
An allylic alcohol contains an OH group on a carbon atom adjacent to a
C—C double bond. Treatment of allylic alcohol A with HCl forms a
mixture of two allylic chlorides, B and C. Draw a stepwise mechanism
that illustrates how both products are formed.
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