Chlorine dioxide (ClO₂) is a disinfectant used in municipal water treatment plants. It dissolves in basic solution producing ClO3 and ClO₂: 2 ClO₂(g) + 2 OH(aq) → ClO3(aq) + ClO₂ (aq) + H₂O(l) The following kinetic data were obtained at 298 K for the reaction. [CIO₂]o (M) [OH-]o (M) Initial Rate (M/s) 0.060 0.030 0.0248 0.020 0.030 0.00827 0.020 0.090 0.0247 Determine the rate law by indicating the values of "x" and "y" in the general rate law below. Rate = k[ClO₂]*[OH-]y Experiment 1 2 3 X = 1 y = 1 b. Calculate the rate constant for this reaction at 298 K. Sig. Figs. are important. M-1. S-1 Rate constant, k = 184.4

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Chlorine dioxide (ClO₂) is a disinfectant used in municipal water treatment plants. It dissolves in basic
solution producing ClO3 and ClO₂":
2 CLO₂(g) + 2 OH (aq) → ClO3(aq) + ClO₂ (aq) + H₂O(l)
›
The following kinetic data were obtained at 298 K for the reaction.
Experiment
[CIO₂]0 (M) [OH-]o (M) Initial Rate (M/s)
1
0.060
0.030
0.0248
2
0.020
0.030
0.00827
3
0.020
0.090
0.0247
Determine the rate law by indicating the values of "x" and "y" in the general rate law below.
Rate = K[ClO₂]X[OH-]Y
X = 1
= 1
y =
OB
b. Calculate the rate constant for this reaction at 298 K. Sig. Figs. are important.
M-1. S-1
Rate constant, k = 184.4
Transcribed Image Text:Chlorine dioxide (ClO₂) is a disinfectant used in municipal water treatment plants. It dissolves in basic solution producing ClO3 and ClO₂": 2 CLO₂(g) + 2 OH (aq) → ClO3(aq) + ClO₂ (aq) + H₂O(l) › The following kinetic data were obtained at 298 K for the reaction. Experiment [CIO₂]0 (M) [OH-]o (M) Initial Rate (M/s) 1 0.060 0.030 0.0248 2 0.020 0.030 0.00827 3 0.020 0.090 0.0247 Determine the rate law by indicating the values of "x" and "y" in the general rate law below. Rate = K[ClO₂]X[OH-]Y X = 1 = 1 y = OB b. Calculate the rate constant for this reaction at 298 K. Sig. Figs. are important. M-1. S-1 Rate constant, k = 184.4
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