phenul-2-butanol is used perfuniery Show how to SynltlherigeS Write balance )equationanamng all organic produet for the reaction(if anyO Conc Naotfformaldehude conc. NaottCN, H"O CN, H+,o ,H heatO CH, CH, Mgi then waterO CH, CH, MgI +H heat

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Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter9: Energy And Chemistry

Section: Chapter Questions

Problem 9.96PAE: 9.96 Most first aid "cold packs" are based on the endothermic dissolution of ammonium nitrate in...

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9.96 Most first aid "cold packs" are based on the endothermic dissolution of ammonium nitrate in water: NH4NO3(s)NH4+(aq)+NO3(aq) H= 25.69 kJ A particular cold pack contains 50.0 g of NH4NO3 and 125.0 g of water. When the pack is squeezed, the NH4NO3dissolves in the water. If the pack and its contents are initially at 24.0°C, what is the lowest temperature that this bag could reach? (Assume that the ammonium nitrate solution has a specific heat of 4.25J g-l K-l, and that the heat capacity of the bag itself is small enough to be neglected.)
When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of neutralization.) At 23.7C, 25.0 mL of 0.475 M H2SO4 is neutralized by 0.613 M KOH in a coffee-cup calorimeter. Assume that the specific heat of all solutions is 4.18J/gC, that the density of all solutions is 1.00 g/mL, and that volumes are additive. (a) How many mL of KOH is required to neutralize H2SO4? (b) What is the final temperature of the solution?
9.29 In which case is heat added to the system: (a) E=43J , w=40J ; or (b) E=31J , w=34J ?
Would the amount of heat absorbed by the dissolution in Example 5.6 appear greater, lesser, or remain the same if the heat capacity of the calorimeter were taken into account? Explain your answer.
For the process A(l) A(g), which direction is favored by changes in energy probability? Positional probability? Explain your answers. If you wanted to favor the process as written, would you raise or lower the temperature of the system? Explain.
Calculate G for the dissolution of both sodium chloride and silver chloride using data from Appendix E. Explain how the values you obtain relate to the solubility rules for these substances.
9.83 A student performing a calorimetry experiment combined 100.0 mL of 0.50 M HCl and 100.0 mL of 0.50 M NaOH in a coffee cup calorimeter. Both solutions were initially at 20.0°C, but when the two were mixed, the temperature rose to 23.2°C. (a) Suppose the experiment is repeated in the same calorimeter but this time using 200 mL of 0.50 M HCl and 200.0 mL of 0.50 M NaOH. Will the T observed he greater than, less than, or equal to that in the first experiment, and why? (b) Suppose that the experiment is repeated once again in the same calorimeter, this time using 100 mL of 1.00 M HCl and 100.0 mL of 1.00 M NaOH. Will the T observed he greater than, less than, or equal to that in the first experiment, and why?
Suppose you have an exothermic reaction with H = 15 kJ and a S of +150 J/K. Calculate G and Keq at 10, 100, and 1000 K.
Suppose you have an endothermic reaction with H = + 15 kJ and a S of 150 J/K. Calculate G and Keq at 10, 100, and 1000 K.
Using the data in the check your learning section of Example 5.5, calculate H in kJ/mol of AgNO3(aq) for the reaction: NaCl(aq)+AgNO3(aq)AgCl(s)+NaNO3(aq)

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phenul-2-butanol is used perfuniery Show how to Synltlherige S Write balance ) equationanamng all organic produet for the reaction(if any O Conc Naotf formaldehude conc. Naott CN, H" O CN, H+,o ,H heat O CH, CH, Mgi then water O CH, CH, MgI +H heat