Carbonyl stretching in transition metal complexes typically occurs in the region 1700 - 2100 cm1. How many bands would you expect for the meridional and facial isomers of an WL3(CO)3 complex (where L = P(OCH3)3, structures below} in this region of the spectrum? %3D L CO L.. „CO „.CO „CO OC L CO ČO Mer-Complex Fac-Complex The compound WL3(CO)3, whose IR spectrum exhibits bands at 1993, 1919 and 1890 cm. What would be the structure of this complex based on the above assignment

Fundamentals Of Analytical Chemistry
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Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.30QAP
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Carbonyl stretching in transition metal
complexes typically occurs in the region 1700 -
2100 cm1. How many bands would you expect
for the meridional and facial isomers of an
WL3(CO)3 complex {where L = P(OCH3)3,
structures below} in this region of the spectrum?
%3D
CO
L..
L
„.CO
„CO
do
OC
L
CO
ČO
Mer-Complex
Fac-Complex
The compound WL3(CO)3, whose IR spectrum
exhibits bands at 1993, 1919 and 1890 cm1.
What would be the structure of this complex
based on the above assignment
Transcribed Image Text:Carbonyl stretching in transition metal complexes typically occurs in the region 1700 - 2100 cm1. How many bands would you expect for the meridional and facial isomers of an WL3(CO)3 complex {where L = P(OCH3)3, structures below} in this region of the spectrum? %3D CO L.. L „.CO „CO do OC L CO ČO Mer-Complex Fac-Complex The compound WL3(CO)3, whose IR spectrum exhibits bands at 1993, 1919 and 1890 cm1. What would be the structure of this complex based on the above assignment
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