Cao (s) (calcium oxide) is the main ingredient of concrete. While mixing Cao with water, the mixture gets hotter rapidly by its own. The chemical equation of the reaction is given below. Cao (s) + H20 (liq) → Ca(OH)2 (s) Based on the above information, which of the following is correct for the above process to mix Cao (s) with water. O a. AH> 0, AS>0, A G <0 O b.AH<0, AS> 0, AG <0 O C. AH<0, AS<0, AG <0 o d.A H> 0, AS> 0, AG>0 O e. AH<0, AS >0, AG>0 O f. AH < 0, AS<0, AG>0
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- The main constituents in vinegar are water and ethanoic acid (CH3COOH). In order to determine the concentration of acid in homemade vinegar, a student titrated 25 cm3 of 001 M NaOH against the vinegar. The equation for the reaction is: CH3COOH(aq) + NaOH(aq) ® CH3COONa(aq) + H2O(l) The following titration results were obtained: Burette readings (cm3) Rough 1 2 Final burette reading 20.10 38.90 31.40 Initial burette reading 0.10 20.00 12.50 Volume of vinegar used 20.00 18.90 18.90 (a) What volume of vinegar should be used in the calculation? (b) What is the mole ratio of NaOH:CH3COOH? (c) Calculate the number of moles of alkali in 25 cm3 of NaOH solution used. (d) How many moles of acid were used in the titration? (e) Calculate the…An unknown mixture is known to contain only Ba(OH)2 (MW=171.34 g/mole) and NaOH (MW=40.0 g/mole). If the mixture is known to contain 45% by mass NaOH, and 8.0 grams of the mixture is dissolved completely in 50.0 ml of solution, answer the following. c).If 10.0 ml of a 0.2 M solution of Na2SO4 was added to the 50.0 ml solution, what would be the final concentration of Na+ in solution.A 1.000-g sample containing bromide was dissolved in sufficient water to give 100.0 mL. A 50.00 mL aliquot was measured and after acidification, silver nitrate was introduced to precipitate AgBr, which was filtered, washed, and then dissolved in an ammoniacal solution of potassium tetracyanonickelate(II): Ni(CN)42- + 2AgBr(s) → 2Ag(CN)2- + Ni2+ + 2Br- The liberated nickel ion required 11.70 mL of 0.002146 M EDTA. The other 50.00 mL remaining solution was also analyzed for its Br- content by potentiometry using a metallic electrode of the second kind. e) Write the cell notation of the potentiometric set-up with SCE as the reference electrode. f) Write the Nernst equation that describes the indicator electrode set-up.
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