According to the mechanism given in the degradation of 12- catalyzed acetaldehyde, subtract the rate expression based only on the rate constants and 12 and acetaldehyde concentration. Note: Apply the steady-state hypothesis for I, CH3CO and CH3. k 12 21 k1 I+CH,CHO–→HI+CH,CO k3 CH,CO- CH, СО —СH, + CО CH, + HI- →CH, +I

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 113QRT
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According to the mechanism given in the degradation of 12-
catalyzed acetaldehyde, subtract the rate expression based
only on the rate constants and 12 and acetaldehyde
concentration. Note: Apply the steady-state hypothesis for I,
СНЗСО and CНЗ.
k
21
2
k1
k2
I+CH,CHO->HI+CH,CO
k3
CH,СО СH, + CO
→CH, +CO
CH, + HI — kyСH, +I
→CH4
Transcribed Image Text:According to the mechanism given in the degradation of 12- catalyzed acetaldehyde, subtract the rate expression based only on the rate constants and 12 and acetaldehyde concentration. Note: Apply the steady-state hypothesis for I, СНЗСО and CНЗ. k 21 2 k1 k2 I+CH,CHO->HI+CH,CO k3 CH,СО СH, + CO →CH, +CO CH, + HI — kyСH, +I →CH4
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