Calculated Heats of Reaction, AH=AHf(R')+ AHf(CH) – AHF(RCD, in kJ/mol: R=n-butyl R= sec-butyl R= tert-butyl R = crotyl Based on their Calculated Heats of Reaction, list these primary, secondary, tertiary, and allylic halides in order of increasing relative rates (slowest < fastest): Why is the allylic cation (crotyl) different in stability compared to a primary cation? (One word:)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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SN1
Gas Phase PM3 Energies (kJ/mol)
AHf(RCI)
AHf(R*)
AHf(CIH)
R=n-butyl
R = sec-butyl
R= tert-butyl
R= crotyl
Calculated Heats of Reaction, AHon= AHf(R")+ AH¡(CH) - AHf(RCI), in kJ/mol:
%3D
R = n-butyl
R = sec-butyl
R= tert-butyl
R= crotyl
Based on their Calculated Heats of Reaction, list these primary, secondary, tertiary,
and allylic halides in order of increasing relative rates (slowest < fastest):
Why is the allylic cation (grotvl) different in stability compared to a primary cation?
(One word:)
Transcribed Image Text:Use Save Image As... from the File menu to save the above molecules as space filling molecules showing the LUMO surface on the carbon as PNG images, then copy and paste to the end of this report. SN1 Gas Phase PM3 Energies (kJ/mol) AHf(RCI) AHf(R*) AHf(CIH) R=n-butyl R = sec-butyl R= tert-butyl R= crotyl Calculated Heats of Reaction, AHon= AHf(R")+ AH¡(CH) - AHf(RCI), in kJ/mol: %3D R = n-butyl R = sec-butyl R= tert-butyl R= crotyl Based on their Calculated Heats of Reaction, list these primary, secondary, tertiary, and allylic halides in order of increasing relative rates (slowest < fastest): Why is the allylic cation (grotvl) different in stability compared to a primary cation? (One word:)
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