C. 2. NO₂ C. match the two NMR spectra below to two of the structures. Justify your answer. The curved line through the middle is the integration of the signal. The further up the curve climbs, the more hydrogens are part of that signal. The first spectrum is annotated for you. 8 23 7 NO₂ 6 6 5 NO₂ 1H 4 8 8 (ppm) Note: The peak above 4 is a septet and the peak below 2 is a doublet. 5 4 8 (ppm) Br 3 3 6H 2 20 2 PETROL CA PPM 0 0 Note: The insets are blow-ups of the peaks at 2.5 and 1 so that you can see the splitting. There is also a peak at 2.1 that is a singlet.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL3: Carbon (13c) Nmr Spectroscopy
Section: Chapter Questions
Problem 12CTQ
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C.
2.
NO₂
C.
match the two NMR spectra below to two of the structures. Justify your answer.
The curved line through the middle is the integration of the signal. The further up the
curve climbs, the more hydrogens are part of that signal. The first spectrum is annotated
for you.
8
23
7
NO₂
6
6
5
NO₂
1H
4
8
8 (ppm)
Note: The peak above 4 is a septet and the peak below 2 is a doublet.
5
4
8 (ppm)
Br
3
3
6H
2
20
2
PETROL
CA
PPM
0
0
Note: The insets are blow-ups of the peaks at 2.5 and 1 so that you can see the splitting.
There is also a peak at 2.1 that is a singlet.
Transcribed Image Text:C. 2. NO₂ C. match the two NMR spectra below to two of the structures. Justify your answer. The curved line through the middle is the integration of the signal. The further up the curve climbs, the more hydrogens are part of that signal. The first spectrum is annotated for you. 8 23 7 NO₂ 6 6 5 NO₂ 1H 4 8 8 (ppm) Note: The peak above 4 is a septet and the peak below 2 is a doublet. 5 4 8 (ppm) Br 3 3 6H 2 20 2 PETROL CA PPM 0 0 Note: The insets are blow-ups of the peaks at 2.5 and 1 so that you can see the splitting. There is also a peak at 2.1 that is a singlet.
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