(c) The data set below represents the surface tension data for aqueous solutions of 3- methylbutanoic acid [(CH3)2CHCH₂COOH] at 25°C. [C] [mol.dm³] 0 Y [mN.m'] 0.009 72.7 64.6 0.026 59.0 0.065 51.3 0.135 47.0 (i) Calculate the surface excess of 3-methylbutanoic acid (in mol.m²) and (ii) Hence estimate the molecular cross sectional area (in nm²) for this surface active molecule. (iii) Compare your estimate with the molecular cross sectional area one might expect for n-butanoic acid and account for the difference, if any, between the two surface active molecules.

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(c) The data set below represents the surface tension data for aqueous solutions of 3-
methylbutanoic acid [(CH3)2CHCH₂COOH] at 25°C.
[C] [mol.dm³] 0
Y[mN.m']
72.7
0.009
64.6
0.026
59.0
0.065
51.3
0.135
47.0
(i) Calculate the surface excess of 3-methylbutanoic acid (in mol.m2) and
(ii)
Hence estimate the molecular cross sectional area (in nm²) for this surface active
molecule.
(iii) Compare your estimate with the molecular cross sectional area one might expect
for n-butanoic acid and account for the difference, if any, between the two surface
active molecules.
Transcribed Image Text:(c) The data set below represents the surface tension data for aqueous solutions of 3- methylbutanoic acid [(CH3)2CHCH₂COOH] at 25°C. [C] [mol.dm³] 0 Y[mN.m'] 72.7 0.009 64.6 0.026 59.0 0.065 51.3 0.135 47.0 (i) Calculate the surface excess of 3-methylbutanoic acid (in mol.m2) and (ii) Hence estimate the molecular cross sectional area (in nm²) for this surface active molecule. (iii) Compare your estimate with the molecular cross sectional area one might expect for n-butanoic acid and account for the difference, if any, between the two surface active molecules.
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