Both (S)-citronellal and isopulegol are naturally occurring terpenes (S)-citronellal is treated with tin(IV) chloride (a Lewis acid) followed by neutralization with aqueous ammonium chloride, isopulegol is obtained in 85% yield. .When H 1. SnCl4, CHCI, 2. NH,CI (S)-Citronellal (C10H180) Isopulegol (C10H180)
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How many stereocenters are present in isopulegol? How many stereoisomers are possible for a molecule with this number of stereocenters?
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- 10:29 0. O ? 86% AIATS For Two Year Medic. A 61 /180 (02:55 hr min Mark for Review When 2-Methylpropene undergoes oxidation in the presence of acidic K2Cr2O7, the products obtained are CH3 – CH + CO2 CH3 — СH — С—ОН-СО, CH, -C =0+CO2 +H2O CH3 CH; – CH2 – CH + CO2 + H20 Clear Response III3. d) FOBICH NaBH/CeCl CH₂OH OS (CH₂CH3)3 1) CH₂0- -3- CuBr S(CH₂) 2) acidity (cold) -MgBr PHCHINH PHOCH NaBH(OCCH33. Consider the reaction scheme below: CH;CHO A CH;MgBr D B CH,CN CH3COOH Y 1. Dry ether 2. H30* E CH;COOCH2CH3 CH3COCI NH3 a) Draw the structural formulae for X, Y and Z b) State the reagent(s) and condition(s) for A, B, C, D and E
- | Exercises 317 9.21 Identify the reactants from which the following molecules were prepared. If an acetal, identify the carbonyl compound and the alcohol; if an imine, identify the carbonyl compound and the amine; if an alcohol, identify the carbonyl compound and the Grignard reagent (red = 0, blue = N): (a) (b) (c)7.Howware these pelatad: (25,3R)2bruma3chloro butane (2R,35) 2bromo 3 choro butanei aybuzem.aybu.edu.tr 曲 Takvim Nişanlar Tüm dersler Site ana sayfası Course dashboard Adipic acid, H2C6H8O4, used to produce nylon, is made commercially by a following reaction between cyclohexane (C&H1 2) and 0,: 2 CH12 +5 02 2 H2C8H&O4 + 2 H20. Assume that you carry out this reaction with 25.0 g of cyclohexane and that cyclohexane is the limiting reactant. If you obtain 33.5 g of adipic acid, what is the percent yield for the reaction? Lütfen birini seçin: O a. 77.0% O b. 57.0% O C. 41.0% O d. 83.0% O e. 64.0% SONRAKİ SAYFA URULAR Geçiş yap. CHAPTER 1 ►
- 18. The addition of H20 to ethene yields a molecule called: (a) ethanol (b) ethane (c) ethyne (d) ethylene glycol3. Draw structural formulas for the major product(s) resulting from the following reactions: OH Cl2 (a) FeCl3 CH3 .CH3 KMNO4, H* Heat (b) Он (c) Br2curri ENO 18) C3 Complete and balance the following reactions a) CH-CH-CH-CH₂ + Bri REAGENTS b) D-Test with potassium permanganate (KMnO4) D.1 Observe the color change. Write (Yes = reaction and NR= no reaction) in the following reactions Condensed structural formulas CI PRODUCTS IF REACTION OCCURS 00:00 Hydrocarbon Cyclohexane (CHz) Cyclohexene (CaH10) Toluene D.2 Draw the condensed structural formula of the reactants and products if any reaction occurred. (CrHe) Reaction with KMnO CICLOHEXANE (C6H12) CICLOHEXENO (C6H10) TOLUENE (CaHo
- "A research team synthesizes a novel organic compound 'X' with the molecular formula C5H8O2. When 'X' is treated with a deuterated acid (D2O), a single deuterium atom replaces a hydrogen atom, forming compound 'Y' (C5H7DO2). 'X' does not react with 2,4-Dinitrophenylhydrazine (2,4-DNP) but does react with both Tollens' reagent and Benedict's solution, forming a silver mirror and a red precipitate, respectively. Furthermore, 'X' undergoes catalytic hydrogenation over a palladium catalyst, consuming one mole of hydrogen to form a compound 'Z' (C5H10O2). Based on these observations, what is the most likely structure of compound 'X'?" A. Methyl vinyl ketone B. 3-Buten-2-one C. Acetoacetic ester D. 2-Hydroxypent-3-enal(b) H CH2CH3 ·C. -CH2CH3 CH3 CH3OH (H)3. Write the structure of the alkene X, that forms the compound below, when treated with ozone (O3) and Zn and Acetic Acid or (CH3)2S workup. X=? X+ (1) Ozone + (2) Zn, Acetic Acid CH